Article
Chemistry, Analytical
Yurong Zhuang, Chenchen Wang, Yong Wang, Yuhui Chen, Songqin Liu, Wei Wei
Summary: It was found for the first time that vanillin and TMB can reduce Tollens' reagent to different types of Ag nanoparticles. Based on this, a dual-mode detection method for vanillin was designed using colorimetry and SERS. This method allows for rapid, visual and highly sensitive detection of vanillin.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Materials Science, Multidisciplinary
Miao Yu, Qihang Tian, Guangyuan He, Kaimin Cui, Jihong Zhang
Summary: Surface-enhanced Raman scattering (SERS) is a novel method for low concentration molecular detection, and tapered fiber SERS probes based on silver nanocubes exhibit high sensitivity. These probes can be used for both qualitative and quantitative analysis, with an optimal cone angle of 8.3 degrees.
ADVANCED FIBER MATERIALS
(2021)
Article
Chemistry, Physical
Swapnil Singh, Aishwarya Agarwal, Anamika Avni, Samrat Mukhopadhyay
Summary: The study demonstrates that electrostatic tethering between surface-modified negatively charged silver nanoparticles and highly positively charged intrinsically disordered N-terminal domain of the prion protein enables highly sensitive protein detection at low concentrations. This novel approach provides a potent and reproducible method for characterizing proteins at nanomolar concentrations.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Analytical
Yu Fukunaga, Makoto Harada, Tetsuo Okada
Summary: Freezing is proposed as an efficient way to enhance sensitivity and reproducibility in SERS measurements, maximizing signal intensity and preparing a high-performance SERS platform through simple methods.
Article
Chemistry, Analytical
Lanxin Xu, Jiali Ma, Guodong Wei, Chenjie Gu, Tao Jiang
Summary: This study introduces a novel self-energized hybrid substrate for surface-enhanced Raman scattering (SERS) technique, utilizing a distinctive piezoelectric polyvinylidene fluoride (PVDF) film and hydrophilic-hydrophobic strategy. By pressing or bending the PVDF film, the enhanced localized electromagnetic field of Ag nanoparticles (Ag NPs) can be rationally induced, leading to tunable ultra-high sensitivity. The quantitative level of detection is further improved by uniformly anchoring and enriching analytes using a facile hydrophilic-hydrophobic strategy.
SENSORS AND ACTUATORS B-CHEMICAL
(2022)
Article
Chemistry, Physical
Xiao-Gang Wang, Jian Wang, Zi-Jin Jiang, Dai-Wen Tao, Xu-Qiang Zhang, Cheng-Wei Wang
Summary: This study successfully fabricated SERS-active substrates with dual-bandgap photonic crystal structures, demonstrating ultra-high sensitivity and stability for trace detection of Rhodamine B, providing significant potential for applications in biomolecular detection and chemical analysis.
APPLIED SURFACE SCIENCE
(2021)
Article
Optics
Mahdi Shariat
Summary: This study demonstrates that plasma printing techniques can be used to directly print silver nanoparticles on various flexible substrates in one step. The technique uses silver nitrate solution as a precursor, which is injected in an aerosol state into a non-thermal plasma jet. The plasma chamber accelerates and reduces the droplets, producing silver nanoparticles, which are then deposited onto polyester fabrics in a controlled manner.
Article
Materials Science, Multidisciplinary
Zhinan Yu, Zhengkun Wang, Jie Zhang
Summary: The study discussed the Raman enhancement mechanism of optical fibers decorated with silver nanoparticles as SERS substrates, focusing on the LSPR of AgNPs and cavity enhancement of a silver capillary. Optimal parameters for coating AgNPs and the formation mechanism based on temperature and velocity field distributions were explored. Experimental results demonstrated a detection limit down to 10(-11) mol/L, with a total enhancement factor of approximately 10(9) and an additional cavity-coupled enhancement effect.
OPTICAL MATERIALS EXPRESS
(2022)
Article
Chemistry, Inorganic & Nuclear
Sujittra Srisung, Nootcharin Wasukan, Mayuso Kuno, Siriprapa Somsri, Narissara Tanjedrew
Summary: This study investigates the structure and interaction behavior of dithizone with silver nanoparticles utilizing a combination of surface-enhanced Raman scattering and density functional theory calculations. The results demonstrate a chemical interaction between dithizone adsorbed on silver nanoparticles, oriented through the sulfur and nitrogen atoms in the molecules.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Mohammad Kamal Hossain, Qasem Ahmed Drmosh
Summary: Silver nanoparticles and silver nanorings with strong electromagnetic near-field distributions were fabricated and demonstrated to have surface-enhanced Raman scattering (SERS) activity. The size and interparticle gaps distribution of the silver nanoparticles were estimated, while the silver nanorings were found to consist of different shapes and sizes of silver clusters. FDTD analysis was conducted to elucidate the electromagnetic near-field distributions of these structures.
Article
Chemistry, Multidisciplinary
Yanzhao Pang, Mingliang Jin
Summary: A highly aligned AgNW array film was prepared using a self-assembly method, which showed excellent signal reproducibility and detection ability at low concentrations. The uniform distribution of hot spots inside the AgNW substrate amplified the SERS signal.
Article
Chemistry, Analytical
Monica Ricci, Beatrice Fortuni, Raffaele Vitale, Qiang Zhang, Yasuhiko Fujita, Shuichi Toyouchi, Gang Lu, Susana Rocha, Tomoko Inose, Hiroshi Uji-I
Summary: The study introduced the use of silver nanowires as endoscopic probes for detecting intracellular Raman signals and proposed an advanced strategy to significantly enhance their performance. By uniformly forming gold structures on the smooth AgNW surface, high surface-enhanced Raman scattering efficiency was achieved, demonstrating applicability for molecular sensing in cells.
ANALYTICAL CHEMISTRY
(2021)
Article
Engineering, Electrical & Electronic
Haihong Niu, Yuxin Xie, Jun Shao, Taibao Ye, Tain Wen Li
Summary: This article reports an easy synthetic method, spin coating, for embedding silver nanoparticles into textured pits with controllable gap on a micro scale. It demonstrates that the engineered nucleation sites for texturing process can effectively control the morphological properties of the photo-anode, leading to improved stability and efficiency of dye sensitized solar cells (DSSCs). The results suggest a new approach for adjusting the morphology and structure of solar cell photo-anodes and obtaining arrayed nanostructures with potential synthesis benefits for DSSCs.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2022)
Article
Chemistry, Analytical
Di Liu, Huimin Gao, Wenji Jiang, Su Yan, Hao Liu, Junjie Chen, Sisi Wen, Wei Zhang, Xu Wang, Bing Zhao, Wei Song
Summary: In this study, three-dimensional Ag aerogel-supported Hg single-atom catalysts were used as an efficient SERS substrate for monitoring enhanced oxidase-like reactions. The effect of Hg2+ concentrations on the SERS properties of 3D Hg/Ag aerogel networks was investigated, and an optimized addition of Hg2+ resulted in specific enhancement. The formation of Ag-supported Hg SACs was confirmed using HAADF-STEM imaging and XPS measurement, and the oxidase-like catalytic mechanism of Hg/Ag SACs was revealed using DFT. This research provides a mild synthetic strategy for fabricating Ag aerogel-supported Hg single atoms with promising prospects in various catalytic fields.
ANALYTICAL CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Laser Assisted, Savita Rani, A. K. Shukla
Summary: The fabrication of silicon nanowires by metal-assisted chemical etching and deposition of silver nanoparticles by the electroless method can be used for SERS detection of organic pollutants. Study shows that increasing the length of SiNWs decreases the enhancement of SERS, and SERS has potential in discriminating mixed dyes.
Article
Chemistry, Analytical
Yujia Ying, Huilin Li
Summary: Enzymes play a crucial role as biological catalysts in accelerating biochemical reactions in living organisms. This study proposes a convenient method for monitoring enzymatic catalytic processes using native top-down mass spectrometry. By exploring the heterogeneity of the chymotrypsin sample and using tandem mass spectrometry, the researchers were able to monitor covalent and noncovalent enzymatic complexes, substrates, and products during catalysis. The results demonstrate that this method has the potential to be a promising tool for characterizing biocatalysts.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Kang Yang, Shuaibo Shi, Jinyu Wu, Shaolong Han, Shengdi Tai, Shishen Zhang, Kun Zhang
Summary: H2O and D2O are important analogues closely related to various industries and monitoring fields. This study successfully distinguishes and detects H2O and D2O by designing a novel eu(III)-macrocycle with dual emitters, Eu-2a, and conducting fluorescence titration experiments.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Julia Kuligowski, Alvaro Perez-Rubio, Marta Moreno-Torres, Polina Soluyanova, Judith Perez-Rojas, Ivan Rienda, David Perez-Guaita, Eugenia Pareja, Ramon Trullenque-Juan, Jose Castell, Marcha Verheijen, Florian Caiment, Ramiro Jover, Guillermo Quintas
Summary: This study introduces a novel variable selection approach called cluster PLS (c-PLS) to assess the joint impact of variable groups selected based on biological characteristics on the predictive performance of a multivariate model. The usefulness of c-PLS is shown using miRNomic and metabolomic datasets obtained from the analysis of liver tissue biopsies.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Meixue Lai, Lijie Zhong, Siyi Liu, Yitian Tang, Tingting Han, Huali Deng, Yu Bao, Yingming Ma, Wei Wang, Li Niu, Shiyu Gan
Summary: This study presents a method for constructing wearable sweat electrolyte sensors using carbon fiber-based solid-contact ion-selective electrodes (SC-ISEs). By using carbon fibers extracted from commercial cloth as electrode material, the cost and reproducibility issues of flexible SC-ISEs were addressed. The results showed that the carbon fiber-based SC-ISEs exhibited reversible voltammetric and stable impedance performances, and had high reproducibility of standard potentials between normal and bending states.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Ke Yang, Ying Liu, Min Deng, Peipei Wang, Dan Cheng, Songjiao Li, Longwei He
Summary: A near-infrared fluorescent probe has been developed to accurately measure the levels of peroxynitrite (ONOO-) in the endoplasmic reticulum (ER) in acute lung injury (ALI). The probe demonstrated rapid response, high selectivity, good sensitivity, and enhanced fluorescence intensity in response to ONOO-. It was successfully used to detect changes in ONOO- levels and showed significant increases in an ALI cell model and an ALI mouse model.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Yanping Wang, Yuemei Chen, Kejun Li, Jinrong Zhou, Xin Yuan, Mei Zhang, Ke Huang
Summary: In this work, a portable analytical system based on point discharge chemical vapor generation atomic emission spectrometry (PD-CVG-AES) coupling with gold filament enrichment was designed. The highly sensitive analysis of Hg2+ indirectly realized the detection of ascorbic acid (AA). The measurement is based on the fact that Ag+ can decrease the concentration of Hg2+ by forming Ag-Hg amalgam in the presence of the reductant SnCl2, while AA can pre-reduce Ag+ to Ag0, leading to the generation of silver nanoparticles (Ag NPs). The developed novel analytical strategy broadens the application of microplasma-based AES and offers a higher level of sensitivity compared to current AA detection techniques.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Yundi Huang, Bo Song, Kaiwen Chen, Deshu Kong, Jingli Yuan
Summary: This study developed two lysosome-targetable background-free TGL probes for efficient and accurate detection of 1O2, which can be used for monitoring endogenous 1O2 concentrations in lysosomes and discriminating variability induced by different photosensitizers. Furthermore, a smart luminescent sensor film was successfully prepared for on-site 1O2 production detection during PDT processes, offering a promising clinical monitoring tool for skin diseases.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Wei Lang, Jia-Mei Qin, Qian-Yong Cao
Summary: A novel polymer-based probe P1 was successfully synthesized for fluorescently ratiometric sensing of H2S with high selectivity and sensitivity. A smartphone sensing platform was constructed to conduct visual quantitative detection of H2S. P1 can be employed in evaluating the level fluctuations of H2S in living cells, testing water samples/wine samples, and monitoring food freshness.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Yuanyuan Qin, Shuda Liu, Shuyun Meng, Dong Liu, Tianyan You
Summary: The study developed a split aptamer-based sandwich-type ratiometric biosensor for the detection of 17 beta-estradiol (E2) using photoelectrochemical and electrochemical assays. The biosensor utilized split aptamer fragments to recognize E2 and trigger a hybridization chain reaction, resulting in the production of double-stranded DNA labeled with CdTe quantum dots. This DNA complex was able to sensitize CdTe quantum dots and generate response signals for E2 detection. The developed biosensor demonstrated high sensitivity and accuracy with two linear ranges and low detection limits.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Siriwan Teepoo, Jongjit Jantra, Khaunnapa Panapong, David Taiwo Ajayi
Summary: A novel immunochromatographic assay based on hyperbranched Au plasmonic blackbodies with a smartphone readout was developed for rapid and sensitive detection of leucomalachite green residues in fish and shrimp products.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Andrea L. Larraga-Urdaz, Borja Moreira-Alvarez, Jorge Ruiz Encinar, Jose M. Costa-Fernandez, Maria Luisa Fernandez-Sanchez
Summary: A major challenge in the 21st century is the development of point-of-care diagnostic tools. In this study, a highly sensitive and simple bioassay using AuNPs and MNAzymes was developed for rapid detection and quantification of miRNA-4739. The proposed strategy shows potential for breast cancer diagnosis.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Xiaohan Zhao, Anyu Wang, Lingzi Zhai, Jiuhe Gao, Sizhe Lyu, Yingshan Jiang, Tian Zhong, Ying Xiao, Xi Yu
Summary: A novel method using polystyrene-coated magnetic nanoparticles for extracting monohydroxy polycyclic aromatic hydrocarbons from urine samples was investigated. The proposed method is simple, sensitive, and efficient, with desirable sensitivity for analyzing low-abundance metabolites in large volumes of complex urine samples.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Ke Quan, Yuqing Zeng, Wenke Zhang, Fengfeng Li, Mengjiao Li, Zhihe Qing, Linlin Wu
Summary: In this study, a visual and reusable biosensor was developed for detecting substrates that are closely associated with human physiological health. The immobilized oxidase showed higher stability and sensitivity under harsh conditions, enabling reliable detection of substrates in complex fluids.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Dongjuan Wang, Xiuqian Ding, Jinling Xie, Juan Wang, Guanhao Li, Xin Zhou
Summary: In this study, a three-in-one sensor was developed for real-time detection of biogenic amines (BAs) with high sensitivity and selectivity. The sensor showed multimodal responses and could be used to fabricate portable devices for on-site non-destructive assessment of food spoilage indicators.
ANALYTICA CHIMICA ACTA
(2024)
Article
Chemistry, Analytical
Jinting Meng, Zihao Xu, Shasha Zheng, Hongqun Yang, Tianfu Wang, Hong Wang, Yingwei Zhang
Summary: This study demonstrates the development of a cascade signal amplification system using a multi-pedal DNA walker and strand displacement reactions for the electrochemical detection of miRNA-155. The biosensor exhibited high sensitivity, selectivity, and the potential for clinical applications.
ANALYTICA CHIMICA ACTA
(2024)