Article
Engineering, Electrical & Electronic
Chedia Ben Ali Hassine, Hamza Kahri, Houcine Barhoumi
Summary: The paper presented a simple method to fabricate a sensor based on Ni nanoparticles and P4NA-modified GCE for simultaneous detection of catechol and hydroquinone. The modified electrode exhibited high sensitivity and selectivity, showing good linear response in a wide concentration range. The sensor was successfully applied for the detection of both analytes in real seawater samples.
IEEE SENSORS JOURNAL
(2021)
Article
Chemistry, Analytical
Fairouz Aberkane, Imene Abdou, Nadia Zine, Nicole Jaffrezic-Renault, Abdelhamid Elaissari, Abdelhamid Errachid
Summary: An electrochemical sensor for melamine detection has been developed using a modified glassy carbon electrode, with a large detection range and low detection limit. The sensor's performance in the presence of various interfering species has also been studied.
Article
Chemistry, Multidisciplinary
Munisamy Maniyazagan, Manzoor Hussain, Woo Seung Kang, Sun-Jae Kim
Summary: There is an urgent need for effective and environmentally friendly photocatalysts due to pollution from organic molecules. Bismuth tungstate nanocomposites have diverse compositions and morphologies, making them suitable for environmental applications. Hierarchical Strontium-based Bismuth tungstate catalysts show enhanced photocatalytic effectiveness against organic contaminants.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Chang Peng, Zeyuan Kuai, Xuezhi Li, Shanshan Lian, Donglin Jiang, Jianfeng Tang, Ling Li, Ruoxi Wu, Anjun Wu, Shu Chen
Summary: A 3D Ag nanoparticles/Ti3C2Tx/polyacrylamide composite hydrogel was designed as a highly efficient catalyst, utilizing synergistic effects to enhance electron transfer and adsorption capacity. This composite hydrogel demonstrated high catalytic activity in reducing methylene blue and 4-nitrophenol, with the added benefit of easy reusability.
MATERIALS & DESIGN
(2021)
Article
Biochemistry & Molecular Biology
Bing Wang, Quanguo He, Guangli Li, Yaohang Long, Gongyou Zhang, Hongmei Liu, Jun Liu
Summary: In this study, a sensitive and selective electrochemical sensor was developed for detecting 4-nitrophenol (4-NP) in natural water samples. The structure, morphology, and electrochemical performance of the electrode modified with formamide-converted nitrogen-carbon material (f-NC) were evaluated. The electrochemical behavior of 4-NP on the f-NC modified electrode was studied. The results showed that the sensor had high selectivity and good stability, enabling the simple, sensitive, and quantitative detection of 4-NP in water samples.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Physical
Munisamy Maniyazagan, Perumal Naveenkumar, Hyeon-Woo Yang, Hassan Zuhaib, Woo Seung Kang, Sun -Jae Kim
Summary: Water contamination is a significant environmental issue in modern times, with dyes and pharmaceutical industries being major sources of pollution. The hierarchical SiO2@FCO core-shell catalyst shows exceptional photocatalytic activity in degrading harmful substances.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Applied
Seyedeh Mina Ghalebi, Hooshang Parham, Abbas Shirmardi
Summary: A glassy carbon electrode (GCE) was modified with poly (methylene disulfide)/Au-nanoparticles/multiwall carbon nanotubes (PMDS/AuNPs/MWCNT) to enhance its detection ability for trace mercury cations in polluted water. Characterization techniques confirmed the success of the modification process and its impact on the electrode morphology and surface roughness. Electrochemical impedance spectroscopy (EIS) showed improved electrochemical properties with decreased charge transfer resistance (R_ct) from 477.1 Ohm cm(2) for unmodified GCE to 83.4 Ohm cm(2) for the modified GCE. The modified electrode was used as an ultra-sensitive sensor for detecting Hg2+ cations using differential pulse anodic stripping voltammetry (DPASV) technique.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Chemistry, Analytical
Veeresh A. Sajjan, Shambhulinga Aralekallu, Manjunatha Nemakal, Manjunatha Palanna, C. P. Keshavananda Prabhu, Lokesh Koodlur Sannegowda
Summary: In this study, a Schiff-base embedded cobalt (II) complex was successfully prepared and characterised, followed by modification of glassy carbon electrode for the electroanalytical detection of 4-nitrophenol. The GCE/CoTTIMPPc exhibited excellent performance in terms of stability, sensitivity, reproducibility and reliability, demonstrating its potential for environmental monitoring applications.
MICROCHEMICAL JOURNAL
(2021)
Article
Environmental Sciences
Van-Dat Doan, Ngoc-Vy Nguyen, Thi Lan-Huong Nguyen, Vy Anh Tran, Van Thuan Le
Summary: In this study, a ternary magnetically separable nanocomposite of silver nanoparticles embedded in magnetic graphene oxide was successfully synthesized and characterized. The material exhibited ultrafast catalytic reduction of organic pollutants with excellent stability and recoverability. Therefore, it holds promise for potential applications in wastewater treatment.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Analytical
Jessica Scremin, Gabriel J. Mattos, Robert D. Crapnell, Samuel J. Rowley-Neale, Craig E. Banks, Elen R. Sartori
Summary: A novel electrochemical sensor utilizing a modified glassy carbon electrode covered with a poly(allylamine hydrochloride) film was proposed in this study, allowing for simultaneous determination of dopamine, paracetamol, amlodipine, and rosuvastatin with linear concentration ranges and low detection limits. This sensor showed successful application in environmental, pharmaceutical, and biological samples for the simultaneous determination of these analytes.
Article
Spectroscopy
Peng Li, Dongxing Yuan, Kunde Lin
Summary: A novel method for determining nanomolar dissolved sulfides in water was proposed in this study, which combines the classical methylene blue method with surface-enhanced Raman spectroscopy detection. The method showed a linear range for sulfides and excellent tolerance to coexisting substances, demonstrating great promise for environmental water analysis.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Engineering, Electrical & Electronic
Ke Cao, Chenxi Si, Haiyan Zhang, Jiahao Hu, Dan Zheng
Summary: In this study, Cu-x-Fe3O4 nanocomposites were successfully prepared and applied for efficient electrochemical sensing detection of 4-NP. The optimal composite, Cu-0.5-Fe3O4, showed a good linear relationship and a low detection limit within the range of 4-NP concentrations. The sensor exhibited high selectivity, strong anti-interference ability, and good stability, making it suitable for the determination of 4-NP in real water samples.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Chemistry, Analytical
Vahid Riahifar, Nahid Haghnazari, Fatemeh Keshavarzi, Elahe Ahmadi
Summary: This study introduced a sensitive sensor for detecting MET based on a modified glassy carbon electrode using Fe3O4@PPy core-shell and ErGO. The sensor was characterized using FE-SEM and EIS, showing better analytical performance compared to other modified electrodes for MET detection. The sensor exhibited a wide linear range and low detection limit, with good reproducibility, sensitivity, and long-term performance, making it a promising candidate for MET determination in urine and serum samples.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Porntip Khownarumit, Kanmanee Choosang, Rungtiva P. P. Poo-arporn, Yingyot Poo-arporn, Narong Chanlek, Werasak Surareungchai
Summary: This study utilized methylene blue as both donor and acceptor for a redox reaction and investigated the detection method for hemoglobin, myoglobin, and cytochrome C through modified electrode surface. The method offers a simple and efficient fabrication platform for electrochemical sensors for hemeproteins.
Article
Chemistry, Physical
Z. G. Qi, Q. Chen, Y. Feng, H. Z. Liu, Z. X. Wang, Z. Q. Song, Z. C. Yan, L. Y. Guo, X. H. Zhang, W. M. Wang
Summary: This work investigates the light activated degradation performance of Methylene Blue (MB) and the magnetic properties of Fe80PxC20-x (x = 0, 4, 7 and 13) glassy ribbons. The Fe80C20 ribbons exhibit a crystalline state, while the Fe80PxC20-x (x = 4, 7 and 13) ribbons show an amorphous state. The degradation efficiency of MB decreases with increasing P content in the ribbons under dark condition, and the stability of Fe-P bonds is higher than Fe-C bonds, indicating the Fe-P bonds release less Fe in the Fenton-like reaction. Under visible light, the degradation efficiency of the ribbons first increases and then decreases with increasing P content, and the ribbon with x = 4 shows the highest efficiency.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Environmental Sciences
R. Suresh, N. S. Karthikeyan, Lalitha Gnanasekaran, Saravanan Rajendran, Matias Soto-Moscoso
Summary: CuO loaded g-C3N4 nanocomposites were prepared by a simple calcination method. The formation of CuO nanocrystals on g-C3N4 was confirmed by XRD, FTIR, and XPS analyses. The addition of CuO nanoparticles reduced the band gap and showed high catalytic efficiency in the reduction of 4-NP and MO.
Article
Environmental Sciences
Lalitha Gnanasekaran, R. Suresh, Saravanan Rajendran, Wei-Hsin Chen, Matias Soto-Moscoso
Summary: In this study, the degradation efficiency of textile dyes by pure cobalt oxide and nickel cobaltite under visible light irradiation was investigated. The synthesized nickel cobaltite showed higher crystallinity and visible light absorption compared to pure cobalt oxide. The excellent degradation efficiency of nickel cobaltite makes it a promising visible light catalyst.
ENVIRONMENTAL RESEARCH
(2023)
Article
Environmental Sciences
Kanagarathinam Saravanan, Balasubramanian Shanthi, Cingaram Ravichandran, Bakthavachalam Venkatachalapathy, Kulathu Iyer Sathiyanarayanan, Saravanan Rajendran, Natesan Sundaramurthy Karthikeyan, Ranganathan Suresh
Summary: Synthesis of aluminium-based nanomaterials from aluminium waste is a hot topic in current scientific research. In this study, aluminium foil food containers were successfully converted into aluminium oxyhydroxide nanoparticles through a precipitation method. The catalytic potential of these nanoparticles in dye reduction was evaluated and found to be highly efficient.
ENVIRONMENTAL RESEARCH
(2023)
Article
Energy & Fuels
R. Suresh, Saravanan Rajendran, Kingshuk Dutta, Kuan Shiong Khoo, Matias Soto-Moscoso
Summary: The aviation industry plays a vital role in global economic growth and social development, but it has negative impacts on the environment. Therefore, the industry is seeking sustainable and clean fuel options, and hydrogen energy is considered a promising choice due to its remarkable advantages. This review focuses on various light assisted hydrogen production techniques, including photofermentation, photochemical methods, and light assisted electrochemical methods. The potential use of wastes as feedstock in these methods and the importance of nanomaterials in light assisted hydrogen production techniques are discussed. The review also explores advancements in improving the rate and yield of hydrogen production, and proposes current challenges for advancing research in this field.
Review
Chemistry, Applied
R. Suresh, Saravanan Rajendran, Kuan Shiong Khoo, Matias Soto-Moscoso
Summary: In recent years, there has been a significant increase in research studies on enzyme immobilized materials for water pollution monitoring and remediation. This review examines the use of enzymes immobilized on nanomaterials for electrochemical sensing and biocatalytic degradation of water pollutants. Advantages and methods of enzyme immobilization on nanomaterials are discussed, as well as the sensing performances and biocatalytic properties of these materials towards various organic pollutants. The review also highlights the significance of nanomaterials in enzymatic sensing and catalytic degradation, identifies current challenges, and provides directions for further research.
TOPICS IN CATALYSIS
(2023)
Review
Environmental Sciences
R. Suresh, Saravanan Rajendran, Lalitha Gnanasekaran, Pau Loke Show, Wei-Hsin Chen, Matias Soto-Moscoso
Summary: This review investigates the application of PVDF-based nanomembranes in the removal of synthetic dyes. Various methods, including surface coating and blending, were discussed for fabricating high performance PVDF-based nanomembranes. The incorporation of nanomaterials such as metal compounds, metals, (synthetic/bio)polymers, metal organic frameworks, carbon materials and their composites in PVDF membranes to enhance their performance was also explored. The impact of nanomaterials on the surface features, mechanical strength, hydrophilicity, crystallinity, and catalytic ability of PVDF membranes was discussed, along with future research directions.
Article
Chemistry, Analytical
Victor Vinoth, Reshma Kaimal, Muthamizh Selvamani, Rubina Michael, Nalandhiran Pugazhenthiran, Ramalinga Viswanathan Mangalaraja, Hector Valdes, Sambandam Anandan
Summary: A facile green approach for the synthesis of graphene quantum dots embedded on silicate network silver nanocrystals (GQDs-AgNCs(APTS)) is reported. The prepared nanocomposite containing graphene quantum dots supported on silver nanocrystals (GQDs-AgNCs(APTS)) was used to modify glassy carbon-GC electrodes for simultaneous detection of guanine (GA) and adenine (AD). The modified electrode exhibited enhanced electrochemical behavior towards the detection of adenine and guanine.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Article
Energy & Fuels
R. Suresh, Lalitha Gnanasekaran, Saravanan Rajendran, Matias Soto-Moscoso
Summary: A green and sustainable energy resource, hydrogen (H2), can be generated via photocatalytic splitting of water to meet global energy demand and minimize environmental pollution. Doped photocatalysts have been extensively studied for their application in water splitting. The influence of metal/non-metal dopants on the properties of host semiconductors was deduced, and the water splitting capacity of metal and non-metal ions doped photocatalysts was discussed. Different host photocatalysts, experimental conditions, and strategies for enhancing activity were summarized, along with challenges, future directions, and conclusions.
Article
Engineering, Electrical & Electronic
Muthamizh Selvamani, Ali Alsulmi, Arunmetha Sundaramoorthy, C. Siva Vadivel, Arul Varman Kesavan
Summary: This study investigated the photocatalytic degradation of Rhodamine B using ZnWO4 nanorods as the photocatalyst. The outcomes showed that ZnWO4 exhibited excellent photocatalytic activity, resulting in the significant breakdown of Rhodamine B in a short amount of time. The study also revealed the intermediate products and photocatalytic mechanism during the degradation process.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Chemistry, Physical
S. Sampurnam, S. Muthamizh, S. Balachandran, V Narayanan
Summary: The objective of this research is to develop a highly efficient ternary pol-yaniline - phosphotungstic acid @ZrO2 nanohybrid photocatalyst for visible light. The nanohybrids were synthesized and characterized. The study found that PANI/PTA-ZrO2 (3:1) exhibited enhanced photocatalytic activity.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Biotechnology & Applied Microbiology
R. Suresh, Lalitha Gnanasekaran, Saravanan Rajendran, Matias Soto-Moscoso, Wei-Hsin Chen, Pau Loke Show, Kuan Shiong Khoo
Summary: In recent years, the combination of photocatalysis and other water purification techniques has emerged as an effective method for decontaminating polluted water. This article provides an overview of adsorptive photocatalysis, photo-Fenton, photo-electrocatalysis, photocatalytic ozonation, sono-photocatalysis, and photo-piezocatalytic techniques developed for degrading organic water pollutants. The use of nanocomposites in the degradation of various organic pollutants through integrated photocatalysis is reviewed, along with the catalytic performances of different nanocomposites and the experimental parameters. The article also introduces the integration of multiple techniques with photocatalysis. The challenges, future perspectives, and conclusions of this literature survey are summarized, providing benefits for researchers in the field of photocatalytic water treatment.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2023)
Article
Chemistry, Physical
Mohammedali Abdullah, Muthamizh Selvamani, Arul Varman Kesavan
Summary: To improve the stability of perovskite photovoltaics, various strategies were adopted, including configuring CsPbI3 with stable and highly interacting HTLs, resulting in increased efficiency. Simulation results showed that CuSbS2 had similar or slightly higher PV efficiency compared to spiroOMeTAD HTL PV. Further research will focus on experimental efficiency and device stability.
SURFACES AND INTERFACES
(2023)
Article
Chemistry, Physical
Md Shahadat Hossain, Baskaran Palanivel, Samuel Lalthazuala Rokhum, Muthamizh Selvamani, Siva Vadivel, Ali Alsulmi, Romulo R. Macadangdang Jr, Arunmetha Sundaramoorthy
Summary: Multiferroic bismuth ferrite nanostructures with 3D nanoparticulate and 2D nanoflaky structures were synthesized through a hydrothermal process. The 2D nanoflaky structures exhibited improved opto-electronic properties and catalytic activity compared to the 3D nanoparticulate structures.
SURFACES AND INTERFACES
(2023)
Article
Chemistry, Physical
Chandrasekar Karuppaiah, Muthamizh Selvamani, Arul Varman Kesavan, Praveen C. Ramamurthy
Summary: To achieve highly efficient photovoltaic, losses in photo-generated charge carrier transport should be minimized by using low resistive and trap free transport path. This can be achieved by maintaining balanced electron and hole mobility, high conducting transport layers, and ideal Schottky and Ohmic contact. In this study, the effect of embedding metal nanoparticles in PEDOT:PSS on photovoltaic performance was investigated. The results show that metal nanoparticles in the hole transport layer can enhance short circuit current density and fill factor, leading to improved power conversion efficiency.
SURFACES AND INTERFACES
(2023)
Article
Chemistry, Physical
Muthamizh Selvamani, S. Balachandran, Arul Varman Kesavan, Victor Vinoth
Summary: In this study, cost-effective nano-flowers Bi2MoO6 were synthesized using a hydrothermal method. The synthesized Bi2MoO6 exhibited a monoclinic phase with a flower-like structure composed of semi-randomly oriented petals. The Bi2MoO6 nano-flowers showed promising anticancer activity against melanoma cells and also demonstrated effective degradation of organic pollutants under visible light irradiation.
SURFACES AND INTERFACES
(2023)