☆ 4.7 Article

Combined reforming of methane by carbon dioxide and water: Particle size effect of Ni-Mg nanoparticles

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2015)

期刊

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

卷 40, 期 38, 页码 12985-12992

出版社

PERGAMON-ELSEVIER SCIENCE LTD

DOI: 10.1016/j.ijhydene.2015.08.011

关键词

CO2-steam reforming; Ni catalysts; Methane; Syngas; Size dependent

类别

Chemistry, Physical Electrochemistry Energy & Fuels

资金

Ferdowsi University of Mashhad, Iran [2/33595-5/12/93]

向作者/读者索取更多资源

Protocol

Reagent

摘要

The effect of Ni-Mg particle size on product selectivity, catalyst activity and coke formation on Ni/MgO/alpha-Al2O3 catalyst were studied in simultaneous steam and CO2 reforming of methane to syngas. The Ni-Mg particle sizes in the range of 13.7-29.7 nm were prepared via incipient wetness impregnation method using alpha-Al2O3 cc as support. Experimental results for turn over frequency (TOP) show that the intrinsic catalyst performances were dependent on Ni-Mg particle size. However, the products selectivities and H-2/CO ration were found to be independent of Ni Mg particle size. The experimental results reveal that the coke formation rates on the surface of catalysts are increased by increasing Ni Mg particle size. Nevertheless, the correlated site carbon atom deposition rates (carbon atoms deposited on one site of catalyst) is shown an opposite trend. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者

点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7

评分不足

次要评分

新颖性

-

重要性

-

科学严谨性

-

评价这篇论文

推荐

Review Chemistry, Physical

A comprehensive review on improving the production of rich-hydrogen via combined steam and CO2 reforming of methane over Ni-based catalysts

Ahmad Salam Farooqi, Mohammad Yusuf, Noor Asmawati Mohd Zabidi, R. Saidur, Khairuddin Sanaullah, Abid Salam Farooqi, Afrasyab Khan, Bawadi Abdullah

Summary: Rapid global energy demand growth has led to increased greenhouse gas emissions, highlighting the importance of utilizing Ni-based catalysts for methane reforming as a sustainable solution. Ni-based catalysts offer cost-effectiveness and high catalytic activity in curbing emissions.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

添加到收藏夹

Review Chemistry, Physical

A review on bi/polymetallic catalysts for steam methane reforming

Siqi Wang, Seyed A. Nabavi, Peter T. Clough

Summary: Blue hydrogen production by steam methane reforming (SMR) with carbon capture is the most commercially viable method, and sorption-enhanced steam methane reforming (SESMR) can further decrease the cost of H2 production. Introducing additional metal elements to improve the performance and prevent catalyst deactivation has been an effective solution. This review summarizes recent developments and highlights the potential of bi/polymetallic catalysts for SMR.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

添加到收藏夹

Article Chemistry, Physical

Steam-promoted Methane-CO2 reforming by NiPdCeOx@SiO2 nanoparticle clusters for syngas production

Yu-Shih Lin, Jia-Yun Tu, De-Hao Tsai

Summary: This study demonstrates a facile aerosol-based method to prepare hybrid nanostructures for catalyzing steam-promoted CO2 reforming with methane. The resulting NiPdOx-CeO2 nanoparticles deposited on SiO2 nanoparticle clusters exhibit superior catalytic performance at low temperatures, with high turnover frequency, tunable H2/CO ratio, and long-term operation stability. Incorporating SiO2 nanoparticle clusters as support material helps to enhance the dispersion of active metals and suppress metal sintering.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

添加到收藏夹

Article Energy & Fuels

Application of hollow promoted Ni-based catalysts in steam methane reforming

Fatemeh Salahi, Fatemeh Zarei-Jelyani, Maryam Meshksar, Mohammad Farsi, Mohammad Reza Rahimpour

Summary: This study focuses on the application of Y-promoted Ni-based catalysts supported on bulk and hollow Al2O3 supports in the steam reforming of methane process. Various characterizing techniques were employed to analyze the catalysts. The 20Ni-3.0Y/HAl catalyst showed the highest methane conversion, hydrogen yield, and H2/CO molar ratio at 700 degrees C, possibly due to the larger surface area of the hollow alumina support compared to the bulk one.

FUEL (2023)

添加到收藏夹

Article Chemistry, Physical

Strong coke-resistivity of spherical hollow Ni/SiO2 catalysts with shell-confined high-content Ni nanoparticles for methane dry reforming with CO2

Mohammadreza Kosari, Saeed Askari, Abdul Majeed Seayad, Shibo Xi, Sibudjing Kawi, Armando Borgna, Hua Chun Zeng

Summary: Hollow nanocatalysts with optimal shell thickness play a crucial role in enhancing reactant conversion and preventing coking hindrance during methane dry reforming reaction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Biomethane reforming over Ni catalysts supported on PrO2-ZrO2 solid-solutions

Yvan J. O. Asencios, Cristiane B. Rodella, Elisabete M. Assaf

Summary: Catalysts based on Ni/PrO2-ZrO2 mixtures show excellent catalytic performance in various reactions. The PrO2-ZrO2 solid solution as a catalytic support can enhance the production of syngas and reduce carbon deposition. In situ characterization of the catalysts reveals that higher PrO2 content helps optimize the catalyst structure and improve activity and stability.

JOURNAL OF CO2 UTILIZATION (2022)

添加到收藏夹

Review Chemistry, Physical

Mesoporous silica supported Ni-based catalysts for methane dry reforming: A review of recent studies

Bernard Chukwuemeka Ekeoma, Mohammad Yusuf, Khairiraihanna Johari, Bawadi Abdullah

Summary: Dry reforming of methane (DRM) is a green alternative for utilizing greenhouse gases and producing syngas. The main limitations of DRM are catalyst sintering and coking. Recent studies have focused on Ni-based catalysts for DRM due to economic constraints on noble metal-based catalysts. Mesoporous silica (MS) supported catalysts show promise due to their high surface areas, thermal stability, and easy availability. However, research on MS as a catalyst support for DRM is still limited.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

添加到收藏夹

Article Chemistry, Physical

Optimized Ni-based catalysts for methane reforming with O2-containing CO2

Guixian Deng, Guifang Zhang, Xing Zhu, Qingjie Guo, Xiangbiao Liao, Xi Chen, Kongzhai Li

Summary: The modification of Ni-based catalysts by CeO2 and ZrO2 suppresses the negative effect of O-2, leading to high CH4 and CO2 conversion rates even at high temperatures. The interaction among Ni, CeO2, and ZrO2 results in well-dispersed Ni particles, contributing to long-term catalyst stability and high conversion rates.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Engineering, Chemical

Contemporary trends in composite Ni-based catalysts for CO2 reforming of methane

Mohammad Yusuf, Ahmad Salam Farooqi, Lau Kok Keong, Klaus Hellgardt, Bawadi Abdullah

Summary: Converting greenhouse gases into valuable syngas through catalytic dry reforming of methane (DRM) is a viable solution, with Ni-based catalysts being extensively used and tested. The main limitation lies in catalyst deactivation due to carbon formation and sintering. Current research focus is on composite catalysts and density functional theory modeling for designing an ideal catalyst.

CHEMICAL ENGINEERING SCIENCE (2021)

添加到收藏夹

Review Chemistry, Physical

Zeolite and clay based catalysts for CO2 reforming of methane to syngas: A review

Hambali Umar Hambali, Aishah Abdul Jalil, Abdulrahman A. Abdulrasheed, Tan Ji Siang, Yahya Gambo, Ahmad Abulfathi Umar

Summary: This review summarizes the recent advances in the development of coke and heat resistant catalysts for the dry reforming of methane (DRM), and discusses the emerging trends in engineered mesostructured catalysts. The review highlights the advances in catalyst synthesis procedures and characterization methods.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

添加到收藏夹

Article Thermodynamics

Steam reforming of biomass tar model compound over two waste char-based Ni catalysts for syngas production

Shuxiao Wang, Yuyuan Zhang, Rui Shan, Jing Gu, Haoran Yuan, Yong Chen

Summary: This paper investigates the catalytic reforming of a tar model compound (benzene) using a novel hybrid carrier catalyst in a laboratory dual-stage reactor. The results show that the catalyst has good benzene removal ability and produces gas products with high syngas content. The catalytic performance is related to surface nanoparticles and abundant active sites.

ENERGY (2022)

添加到收藏夹

Article Engineering, Chemical

Ni-based catalysts supported on MgAl2O4 with different properties for combined steam and CO2 reforming of methane

Shiyi Yu, Yuanwu Hu, Hongjie Cui, Zhenmin Cheng, Zhiming Zhou

Summary: Three MgAl2O4 spinels prepared using different methods showed varied properties when used as supports for Ni catalysts. Among them, MgAl2O4(sg) exhibited the best performance in terms of catalytic activity and stability for CSCRM.

CHEMICAL ENGINEERING SCIENCE (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Embedded Structure of Ni@PSi Catalysts for Steam Reforming of Methane

Cong Suo, Yang Liu, Xiao Zhang, Haiyan Wang, Bingbing Chen, Jiancong Fang, Zhenguo Zhang, Ruoyu Chen, Rui Chen, Chuan Shi

Summary: This study presents a method of preparing embedded Ni@PSi catalysts by adjusting the reduction temperature, which effectively prevents the sintering of Ni nanoparticles and maintains stability. The optimized reduction temperature of 600 degrees C results in a catalyst with high reaction rate and stability.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2022)

添加到收藏夹

Article Engineering, Environmental

Plasma-catalytic reforming of biogas into syngas over Ni-based bimetallic catalysts

Danhua Mei, Xiaoqiang Shen, Shiyun Liu, Rusen Zhou, Xuchu Yuan, Zhiqiang Rao, Yifei Sun, Zhi Fang, Xuesen Du, Ying Zhou, Xin Tu

Summary: This study achieved plasma-catalytic dry reforming of biogas using Ni-based bimetallic catalysts, which resulted in high conversion, yield and selectivity of key gas products, and high fuel production efficiency (FPE). The coupling of DBD with 10Ni3Co showed the best reaction performance, and also helped suppress carbon deposition and reduce energy costs. The use of Ni-based catalysts allowed for tuning of product distribution, favoring the generation of C3-C4 hydrocarbons and syngas. The 10Ni3Co catalyst exhibited superior performance due to factors such as higher specific surface area, improved CO2 adsorption capability, strong metal-support interactions, enhanced reducibility, and Ni-Co alloy formation.

CHEMICAL ENGINEERING JOURNAL (2023)

添加到收藏夹

Article Chemistry, Physical

Upgrading of Bio-Syngas via Steam-CO2 Reforming Using Rh/Alumina Monolith Catalysts

Woo Jin Lee, Chaoen Li, Jim Patel

Summary: The study investigated the steam-CO2 reforming of biomass derived synthesis gas using Rh-loaded alumina foam monolith catalysts, showing that the steam concentration in the feed plays a crucial role in determining the reaction products and pathways. Higher steam concentration favored steam methane reforming and water gas shift reaction, while increasing temperature enhanced methane dry reforming and reverse-water gas shift reaction.

CATALYSTS (2021)

添加到收藏夹

Article Chemistry, Physical

Carbon Dioxide Absorption by the Imidazolium-Amino Acid Ionic Liquids, Kinetics, and Mechanism Approach

Mojtaba Rezaeian, Mohammad Izadyar, Ali Nakhaei Pour

JOURNAL OF PHYSICAL CHEMISTRY A (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Water-gas-shift reaction over nickel catalysts: DFT studies and kinetic modeling

Ali Nakhaei Pour, Sayyed Faramarz Tayyari

STRUCTURAL CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Physical

Effects of metallic cobalt crystal phase on catalytic activity of cobalt catalysts supported on carbon nanotubes in Fischer-Tropsch synthesis

Ali Nakhaei Pour, Mohammadreza Housaindokht

PROGRESS IN REACTION KINETICS AND MECHANISM (2019)

添加到收藏夹

Article Medicine, Research & Experimental

Multifunctional CuO nanoparticles with cytotoxic effects on KYSE30 esophageal cancer cells, antimicrobial and heavy metal sensing activities

Zahra Nakhaeepour, Mansour Mashreghi, Maryam M. Matin, Ali NakhaeiPour, Mohammad Reza Housaindokht

LIFE SCIENCES (2019)

添加到收藏夹

Article Engineering, Chemical

Structural Effects of HZSM-5 Zeolite on Methanol-to-Propylene Reaction

Shahira Islamdoost Jami, Ali Nakhaei Pour, Ali Mohammadi, Seyed Mehdi Kamali Shahri

CHEMICAL ENGINEERING & TECHNOLOGY (2020)

添加到收藏夹

Article Chemistry, Physical

Experimental and simulation study of the effect of surface functional groups decoration on CH4 and H2 storage capacity of microporous carbons

Shohreh Mirzaei, Ali Ahmadpour, Akbar Shahsavand, Ali Nakhaei Pour, Leila LotfiKatooli, Ali Garmroodi Asil, Babak Pouladi, Arash Arami-Niya

APPLIED SURFACE SCIENCE (2020)

添加到收藏夹

Article Chemistry, Applied

Molecular simulation of adsorption and diffusion of H2/CO2/CO/MeOH/EtOH mixture into the zeolitic imidazolate framework ZIF-8

Zahra Keyvanloo, Ali Nakhaei Pour, Fatemeh Moosavi

Summary: The adsorption and diffusion behaviors of H-2, CO2, CO, MeOH, and EtOH in ZIF-8 were studied in pure and mixed states. The results showed different trends for the diffusion coefficients and adsorption isotherms of the guest molecules. The separation of MeOH from other molecules in the mixture was also investigated.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

添加到收藏夹

Article Engineering, Chemical

Fischer-Tropsch Synthesis by a Cobalt-Based Carbon Aerogel Catalyst

Farzad Haghighi, Ali Ahmadpour, Ali Nakhaei Pour

Summary: Carbon aerogel was synthesized as a novel catalyst support for Fischer-Tropsch synthesis. Cobalt-doped carbon aerogel catalysts were synthesized using different strategies, and the size of cobalt particles affected the methane selectivity. Hydrogen spillover from the support to metallic particles improved reducibility and enhanced the production of hydrogenated products.

CHEMICAL ENGINEERING & TECHNOLOGY (2023)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Kinetic study of the crystallization of ZSM-5 under organic template-free conditions

Ali Nakhaei Pour, Ali Mohammadi

Summary: In this study, ZSM-5 zeolite was prepared without organic templates using a hydrothermal process, and the synthesis kinetics were investigated based on crystal growth. The results showed that increasing the Na+ content in the initial gel composition decreased the activation energy for crystal growth and enhanced the crystallization rate of ZSM-5 zeolite.

INORGANIC AND NANO-METAL CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Effect of ZSM-5 zeolite porosity on catalytic cracking of n-heptane

Ali Nakhaei Pour, Ali Mohammadi

Summary: This study investigated the effect of synthesis conditions on the crystal growth, structural features, acidity, and catalytic properties of hierarchical ZSM-5 zeolite in n-heptane cracking. The results showed that the crystallization rate of hierarchical ZSM-5 increased with the amount of SiO2 and Na2O in the initial gel, as well as the reaction temperature. Additionally, by adjusting the initial gel composition and reaction temperature, the porosity, acidity, and crystal size of hierarchical ZSM-5 could be controlled. The selectivity of ethylene and propylene in the heptane cracking reaction was found to be influenced by the acidity and micropore to mesopore ratio of the prepared zeolites, as predicted by both experimental and simulation results.

NEW JOURNAL OF CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Oxidative desulfurization of dibenzothiophene via layered graphitic carbon nitride-coordinated transition metal as a catalyst

Mehdi A. Shadmehri, Mohammad Reza Housaindokht, Ali Nakhaei Pour

Summary: Graphitic carbon nitride (g-C3N4) was synthesized and used in the ODS process with cobalt doping (CoO/g-C3N4) to investigate its catalytic properties. The study found that the cobalt content loaded in the catalyst had the most significant impact on conversion efficiency, while the addition of cyclohexanone negatively affected efficiency.

NEW JOURNAL OF CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Determination of the Product Selectivity Model from the Fischer Tropsch Synthesis in a Fixed Bed Reactor

Y. Ghiasi, H. Atashi, A. Zamanian, A. Nakhaei Pour

PHYSICAL CHEMISTRY RESEARCH (2019)

添加到收藏夹

Article Nanoscience & Nanotechnology

Hydrogen Adsorption by G-C3N4 and Graphene Oxide Nanosheets

Siroos Rostami, Ali Nakhaei Pour, Mohammad Izadyar

JOURNAL OF NANOSTRUCTURES (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Performance and structural features of LaNi0.5Co0.5O3 perovskite oxides for the dry reforming of methane: influence of the preparation method

Maryam Mousavi, Ali Nakhaei Pour

NEW JOURNAL OF CHEMISTRY (2019)

添加到收藏夹

Article Engineering, Chemical

Robust Prediction of Filtrate Flux for Separation of Catalyst Particles from Wax Effluent of Fischer-Tropsch Bubble Column Reactor via Regularization Network

A. Garmroodi Asil, A. Nakhaei Pour, Sh Mirzaei

CHEMICAL PRODUCT AND PROCESS MODELING (2019)

添加到收藏夹

暂无数据

© Peeref 2019-2024. All rights reserved.