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High Reactive MgO-Y2O3 Nanopowders via Microwave Combustion Method and Sintering Behavior

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WILEY
DOI: 10.1111/ijac.12484

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  1. National Nature Science Foundation of China [51472146]

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To decrease the sintering temperature of MgO-Y2O3 composites to avoid undesired grain coarsening, high reactive MgO-Y2O3 nanopowders were synthesized via microwave combustion method. The degree of combustion was enhanced effectively by adding an extra oxidant ammonium nitrate. The as-synthesized MgO-Y2O3 nanopowders, similar to 18nm in size, showed high specific surface area of 64.55m(2)/g and low agglomeration. Relative density of 98% was obtained when sintered at a low sintering temperature of 1350 degrees C. The high reactivity can be attributed to the lower activation energy Q (131.13kJ/mol), compared with samples without extra oxidant (192.97kJ/mol).

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