期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 356, 期 14-15, 页码 3099-3105出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400360
关键词
C-H activation; copper catalysis; cross-dehyrogenative coupling; thioesters
资金
- Department of Science and Technology (DST), New Delhi [SB/S1/OC-53/2013]
- Council of Scientific and Industrial Research (CSIR) [02(0096)/12/EMR-II]
- CSIR
A unique copper-catalyzed cross-dehydrogenative coupling (CDC) of thiols and alkylbenzenes has been developed for the synthesis of thioesters without the assistance of any directing group. A thioester moiety is created via successive C-S and C-O bond formation at the expense of three sp(3) C-H bonds of the alkylbenzene and one sp(3) S-H bond of the thiol.
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