期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 356, 期 10, 页码 2203-2208出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400405
关键词
amino acids; asymmetric synthesis; central and axial chirality; nickel; Schiff bases
资金
- IKERBASQUE
- Basque Foundation for Science
- Basque Government [SAIOTEK S-PE13UN098]
- Hamari Chemicals (Osaka, Japan)
- Regional Development Fund - investing in your future - of the European Union
- State of North Rhine Westphalia
- National Natural Science Foundation of China [81025017]
A new multipurpose glycine equivalent for the general asymmetric synthesis of alpha-amino acids is introduced. The chiral reagent can be transformed to various amino acids by alkylations with alkyl halides as well as aldol and Michael addition reactions under operationally convenient reaction conditions at room temperature with virtually complete stereochemical control.
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