期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 355, 期 11-12, 页码 2191-2196出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201300488
关键词
acyl radicals; aldehyde CH bonds; metal-free conditions; oxidative annulation; TBAB-promoted reactions
资金
- National Natural Science Foundation of China [20972099]
- Beijing Municipal Education Commission Foundation [KZ201210028035]
- Capital Normal University
A metal-free intramolecular annulation of 2-aryloxybenzaldehydes to xanthones is disclosed, which proceeds through the direct oxidative coupling of an aldehyde CH bond and aromatic CH bonds using tetrabutylammonium bromide (TBAB) as a promoter in aqueous medium. This strategy works smoothly in the presence of both electron-donating and electron-withdrawing groups, and displays good tolerance towards catalytically reactive substituents, thus promising further functionalizations of xanthone products.
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