期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 16, 页码 2949-2953出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200659
关键词
aldehydes; amides; iron; radical reactions
资金
- Regione Autonoma della Sardegna
A new direct conversion of aldehydes to amides has been realized, in the presence of iron(III) chloride as a catalyst and using tert-butyl hydroperoxide (TBHP) as an oxidant. Both aliphatic and aromatic aldehydes were successfully reacted with variously mono- and di-substituted N-chloroamines. The methodology has a wide substrate scope, uses cheap and easily available reagents and is characterized by short reaction times.
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