期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 17, 页码 3180-3186出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200748
关键词
carbon dioxide (CO2); formic acid (HCOOH); ionic liquids; syngas; triruthenium dodecacarbonyl [Ru-3(CO)(12)]
资金
- Regione Autonoma della Sardegna [J71 J1 0000250002]
- Effetti sul SNC di una libreria di donatori di nitrossido derivati dall'acido di Piloty [CRP1 409]
- Promozione della Ricerca Scientifica e dell'Innovazione Tecnologica in Sardegna
In light of the growing scarcity of petroleum-based raw materials, carbon dioxide (CO2) is becoming increasing attractive as organic carbon source. In this perspective, formic acid (HCOOH) might be an interesting bio-renewable solution to store, transport, and activate carbon dioxide for the synthesis of value-added chemicals. Herein, HCOOH has been successfully used as C-1 building block for the synthesis of a library of alcohols via a catalysed oxo-synthesis, under green experimental conditions.
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