4.7 Article

Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide-Functionalized NHC Ligand

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 5, 页码 807-812

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100897

关键词

asymmetric catalysis; carbene ligands; hydrosilylation; iridium; ketones

资金

  1. Japan Society for the Promotion of Science (JSPS) [23550128]
  2. A-STEP from Japan Science and Technology Agency (JST) [AS231Z00460D]
  3. Kansai University
  4. Grants-in-Aid for Scientific Research [23550128] Funding Source: KAKEN

向作者/读者索取更多资源

An enantioselective hydrosilylation of prochiral ketones was achieved by using a catalytic amount of the readily accessible and air- and moisture-stable iridium complex [IrCl(cod)(NHC)] at room temperature.

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