期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 11-12, 页码 2135-2140出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200195
关键词
C-H activation; olefin coupling partners; olefination; palladium; pyridines
资金
- State Key Laboratory of Applied Organic Chemistry
A novel and efficient protocol for the C-2 selective olefination of pyridines via a palladium-catalyzed oxidative cross-coupling reaction has been developed. A wide range of pyridines and olefin substrates including acrylic ester, styrene, and acrylamide are compatible. The products are highly useful building blocks for the synthesis of bioactive alkaloid natural products and drug molecules.
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