期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 10, 页码 1897-1901出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200207
关键词
amination; Buchwald-Hartwig cross-coupling; N-heterocyclic carbene; palladium
资金
- EC
- EaStCHEM School of Chemistry
- Royal Society
The well-defined [Pd(IPr*)(cinnamyl)Cl] complex is reported as one of the best N-heterocyclic carbene (NHC)-based pre-catalysts for the BuchwaldHartwig amination reaction. This catalytic system displays high efficiency for the coupling of numerous (hetero)aryl chlorides, with a wide range of amines, at room temperature or at extremely low catalyst loading (as low as 0.025 mol%).
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