期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 5, 页码 828-834出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100806
关键词
allylsilanes; cyclopropanation; palladacyclobutenes; palladium carbenoids; p-allylpalladium species
资金
- Ministry of Education, Culture, Sports, Sciences, and Technology of Japan
- Grants-in-Aid for Scientific Research [22750086] Funding Source: KAKEN
The palladium-catalyzed cyclopropanation of strained alkenes with 3-trimethylsilyl- or 3-pinacolatoboryl-1-arylallyl acetate derivatives is described. This reaction gives cyclopropanation products in good to high yields with a single diastereomer, and the key step is likely to involve the formation of a palladacyclobutene complex from the a-trimethylsilyl- or a-pinacolatoboryl-s-allylpalladium complex.
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