期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 7, 页码 1264-1268出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100936
关键词
alkynes; boron nitride; diethylenetriamine (DETA); heterogeneous catalysis; Pd; BN catalyst; semihydrogenation
The simple preparative method for a novel palladium supported on boron nitride catalyst (Pd/BN) was accomplished. Pd/BN is widely applicable for the semihydrogenation of mono- as well as disubstituted alkynes to furnish the corresponding alkenes in the presence of diethylenetriamine (DETA), which exhibits both an unprecedented acceleration effect toward the semihydrogenation and a suppression effect with regard to the overhydrogenation to alkanes.
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