期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 2-3, 页码 489-496出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100545
关键词
amines; carbamates; carbonylation reactions; palladium-catalyzed reactions; ureas
资金
- National Natural Science Foundation of China [NSFC-21002077]
- Northwest University [PR09037]
- Education Department of Shaanxi Provincial Government [2010JK869]
Switchable access to carbamates and ureas has been developed by solvent control palladium-catalyzed carbonylation of aromatic amines under an atmosphere of carbon monoxide. A variety of N-phenylcarbamates and N,N'-diphenylureas was easily synthesized in good to excellent yields from readily available aromatic amines under mild conditions.
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