期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 354, 期 16, 页码 3095-3104出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201200191
关键词
aldehydes; diastereoselectivity; heterocycles; ionic liquids; multicomponent reactions
资金
- Center of Excellence of Chemistry
- Research Council of the University of Isfahan
An efficient protocol for the excellent diastereoselective synthesis of pyrazolines via a three-component reaction of aldehydes, hydrazines and dimethyl acetylenedicarboxylate (DMAD) in the presence of a bifunctional Bronsted acidic ionic liquid as a reusable catalyst under solvent-free conditions is reported. Easy work-up, short reaction times, high yields of the products and an environmentally benign procedure avoiding toxic organic solvents are other significant features of this method.
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