期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 2-3, 页码 392-400出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000644
关键词
annulation; cascade reactions; gold catalysis; heteroenyne metathesis; phenanthrene
资金
- National Natural Science Foundation of China [20872163, 20732008, 20821002]
- Chinese Academy of Science, Science and Technology Commission of Shanghai Municipality [08QH14030]
- Major State Basic Research Development Program [2006CB806105]
A rapid access to highly substituted phenanthrenyl ketones through gold-catalyzed cyclization of 1,6-diyn-4-en-3-ols with furans has been developed. Gold catalysts are effective to catalyze three cascade processes involving Friedel-Crafts/furan-yne cyclization/heteroenyne metathesis through C-O bond and alkyne activation. This method offers several advantages such as high selectivities and easily accessible starting materials.
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