期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 353, 期 8, 页码 1317-1324出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201100017
关键词
asymmetric transfer hydrogenation; catalyst recycling; enantioselectivity; magnetic nanoparticles; magnetic separation
资金
- China National Natural Science Foundation [20673072]
- Shanghai Sciences and Technologies Development Fund [10J1400103, 10JC1412300]
- Shanghai Municipal Education Commission [S30406]
Two magnetic chiral iridium and rhodium catalysts were prepared via directly postgrafting 1,2-diphenylethylenediamine-derived organic silica or 1,2-cyclohexanediamine-derived organic silica onto the silica-coated iron oxide nanoparticles followed by complexation with iridium(III) or rhodium(III) complexes. During the asymmetric transfer hydrogenation of aromatic ketones in aqueous medium, the magnetic chiral catalysts exhibited high catalytic activities (up to 99% conversion) and enantioselectivities (up to 92% ee). Both catalysts could be recovered easily by magnetic separation and be reused ten times without significantly affecting their catalytic activities and enantioselectivities.
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