期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 9, 页码 1434-1440出版社
WILEY-BLACKWELL
DOI: 10.1002/adsc.201000165
关键词
asymmetric catalysis; Cinchona alkaloids; click chemistry; ketene dimerization; supported catalysts
资金
- University of Pisa, MIUR
- ICCOM-CNR
A convenient route for the covalent immobilization of quinidine and hydroquinidine pyridazine ethers on insoluble polystyrene supports is described, which avoids the need of chromatographic purifications at any stage. The use of the heterogeneized alkaloid derivatives in the asymmetric organocatalytic dimerization of ketenes afforded high enantioselectivity values (90-97% ee) in the course of 20 reaction cycles.
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