期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 352, 期 11-12, 页码 1841-1845出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201000185
关键词
asymmetric synthesis; cyclic carbonyl compounds; hydrogenation; iridium; oxazoline
资金
- National Natural Science Foundation of China [20772081]
- Science and Technology Commission of Shanghai Municipality [09431902500]
- Nippon Chemical Industrial Co, Ltd
By using the iridium complex of a phosphine-oxazoline ligand with an axis-unfixed biphenyl backbone, a highly enantioselective hydrogenation of the C=C bond of exocyclic alpha,beta-unsaturated carbonyl compounds to afford a-chiral cyclic ketones, lactones and lactams was developed.
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