期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 350, 期 9, 页码 1235-1240出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200800089
关键词
heterogeneous catalysis; iron; Lewis acids; magnetic properties; multicomponent reactions; synthetic methods
A new catalyst for an old material: magnetite is an excellent Lewis acid catalyst for the four-component aza-Sakurai reaction. The process could be repeated up to 15-times without losing effectiveness, with the catalyst recycling being as easy as the use of a simple magnet. The catalyst is selective and could discriminate between aldehyde and ketone functionalities, catalyzing first the reaction with the higher electrophilic aldehyde.
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