期刊
ADVANCED MATERIALS
卷 23, 期 22-23, 页码 2617-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201004064
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资金
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft (DFG)
- European Union [COST D-41]
Ionic liquids (ILs), such as [BMIM][Tf2N], on well-defined SCILL model catalysts are able to replace weakly adsorbed CO. On Pt, on-top CO remains adsorbed under the ionic liquid layer, but its IR signal red-shifts by over 30 cm(-1). IL-adsorbate interactions are mediated by the noble metal and similar to ligands.
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