期刊
ADVANCED FUNCTIONAL MATERIALS
卷 24, 期 42, 页码 6668-6676出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201401854
关键词
transparent electrodes; metal thin films; flexible contacts; organic solar cells
类别
资金
- Bundesministerium fur Bildung und Forschung (BMBF) [03IPT602A]
- excellence cluster cfaed
Highly transparent electrodes are demonstrated based on thermally evaporated calcium:silver blend thin-films, which show unusually high transmission well above the expectations from bulk material properties and thin film optics. These electrodes exhibit a low sheet resistance of 27.3 /?, combined with an extraordinarily high mean transmittance of 93.0% in the visible spectral range (sigma(dc)/sigma(opt) = 186.7), superior to the commonly used inorganic electrodes made from indium tin oxide (ITO). Additionally, the metal blend electrode is flexible, showing a constant sheet resistance down to a bending radius of 10 mm and can be employed on top of organic devices without causing damage to the organic material. The spontaneously formed unique microstructure of a polycrystalline Ag network with randomly distributed nanoapertures, surrounded by a calcium shell, enables broadband transmittance enhancement due to amplified plasmonic coupling. Consequently, top-illuminated organic solar cells using such metal blend electrodes achieve a power conversion efficiency of 7.2% (which defines a new record for top illuminated organic solar cells) and even exceed the efficiency of similar bottom-illuminated reference solar cells (6.9%) employing common ITO electrodes.
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