期刊
ADVANCED FUNCTIONAL MATERIALS
卷 19, 期 6, 页码 860-865出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.200801580
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资金
- NSFC [20725102, 50772056]
- Foundation for the Author of National Excellent Doctoral Dissertation
- Chinese Ministry of Education
- Folk Ying Tung Education Foundation [111012]
- State Key Project of Fundamental Research for Nanoscience and Nanotechnology [2006CB932301]
Monodisperse fullerene-like polyoxometalate-based microspheres are synthesized using a single-phase approach which is quick, easier to control surfactant to polyoxometalate (POM) molar ratios and result in better control over the size-distribution range. Noble-metal nanocrystals are successfully incorporated in the surfactant encapsulated complex multilayered spherical assemblies without any change in their layered morphology. Combining the merits of fullerene-like POMs and monodisperse noble metal nanocrystals, these monodisperse hybrid spheres show interesting composition- and size- dependent photochemical properties.
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