期刊
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
卷 15, 期 5-6, 页码 429-437出版社
SPRINGER
DOI: 10.1007/s10450-009-9192-7
关键词
Mesoporous material; Mesocellular siliceous foam; Melamine dendrimer; Functionalization; CO2 adsorption
Melamine-type dendrimers are grafted to mesocellular siliceous foam (MCF) with ultralarge mesopores by stepwise alternating treatments of the substrate with 2,4,6-trichlorotriazine and ethylenediamine. MCF grafted dendrimers up to 4th generation are prepared and characterized. Very high organic loadings (55 wt% at the 4th generation) are achieved, with half of the initial substrate mesopores volume remaining unoccupied-leaving room for the rapid ingress and egress of small gas molecules. The product materials possess relatively high thermal stability-their decomposition starts at around 300 A degrees C. Adsorption measurements suggest that only the primary amine groups of these melamine type structures are active for CO2 chemisorption. The CO2 adsorption capacities of these adsorbents are improved relative to the unfunctionalized MCF, especially when considered on a wt% substrate basis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据