4.7 Article

Grain boundary embrittlement by Mn and eutectoid reaction in binary Fe-12Mn steel

期刊

ACTA MATERIALIA
卷 61, 期 11, 页码 4022-4034

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2013.03.016

关键词

Auger electron spectroscopy; Grain boundary embrittlement; Grain boundary segregation; High Mn steel; Eutectoid reaction

资金

  1. GIFT initiative project program [4.0008189.02]

向作者/读者索取更多资源

The grain boundary embrittlement in a binary Fe-12Mn is due to the grain boundary segregation of Mn. During tempering at 400 degrees C (higher than the equilibrium eutectoid reaction temperature 247 degrees C), reverted austenite particles were formed at lath and grain boundaries through the equilibrium reaction of lath martensite to ferrite austenite. Surprisingly, hydrostatic pressure, which is induced by the transformation of epsilon martensite to austenite during heating at the tempering temperature, resulted in the nonequilibrium eutectoid reaction producing alpha-Mn precipitates at the interface between lath martensite and the transformed austenite during the tempering. The segregation concentration kinetics of Mn formed a convex profile due to the active grain boundary precipitation of the reverted austenite particles and the alpha-Mn particles, which act as a sink for the segregated Mn. Finally, the convex segregation profile of Mn corresponded to the concave profile of intergranular fracture strength. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Kinetic Model to Investigate the Effect of Cooling Rate on δ-Ferrite Behavior and Its Application in Continuous Casting of AISI 304 Stainless Steel

Tahereh Zargar, Fazlollah Sadeghi, Jong Wan Kim, Jae Sang Lee, Yoon-Uk Heo, Chang Hee Yim

Summary: The Thermo-Calc software was used to predict the M-shaped delta-ferrite content in continuously cast 304 austenitic stainless steel slab, with the moving-boundary model showing accurate results when compared to observations. Analysis of different cooling rates revealed a more significant reduction in delta-ferrite under fast solidification rates.

METALS AND MATERIALS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Interfacial reaction and side effect of MgB2 superconducting material through low-rotation mechanical milling

Minoru Maeda, Yoon-Uk Heo, Jun Hyuk Choi, Dipak Patel, Su-Hun Kim, Seungyong Hahn, Jung Ho Kim, Seyong Choi

Summary: Powder processing by ball milling is an effective method for structural modification of superconducting materials. Low-rotation shaker was used to achieve structural modification by controlling processing parameters and enhancing energy transfer. The morphological changes of the processed powders influenced the void structure and composition of the materials.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Multidisciplinary

AlN-assisted internal oxidation behavior in Al-containing high Mn steels

Dongwon Lee, Yoon-Uk Heo, Jae Sang Lee, Won-Tae Cho, Unhae Lee, Myeong-Hun Kang, Chang Hee Yim

Summary: The role of AlN on the internal oxidation behavior in Al-containing high Mn steels was investigated. The results confirmed that increased Al contents led to accelerated internal oxidation. Sequential formation of internal oxidation and AlN + gamma-matrix layers was observed in the steel after heat treatment in air.

MATERIALS CHARACTERIZATION (2022)

Article Metallurgy & Metallurgical Engineering

Nanosized Lamellar Structures and Tensile Properties of Intercritical-Annealed Medium Mn Steels Containing Multiphases

Thi Thanh Tram Trang, Chang-Gon Jeong, Dongwon Lee, Yoon-Uk Heo

Summary: The effect of extended intercritical annealing time on the microstructure and tensile properties of a medium Mn steel is studied. Nanosized lamellar structures consisting of tempered-alpha ' martensite and retained austenite are formed after intercritical annealing. The fraction of cementite and fresh alpha ' martensite increases with extended annealing time, leading to reduced austenite fraction after quenching.

STEEL RESEARCH INTERNATIONAL (2023)

Article Metallurgy & Metallurgical Engineering

Effect of Reheating Temperatures on Hot Ductility and Precipitation Behavior of Low-Carbon Steels

Fazlollah Sadeghi, Tahereh Zargar, Muhamad Rasyad Arkan Lahino, Hyeju Kim, Sang-Hum Kwon, Yoon-Uk Heo, Jae Sang Lee, Chang Hee Yim

Summary: The influence of reheating temperatures on hot ductility was investigated in two Ni-, Mo-, and Cu-containing low-carbon steels. It was found that higher reheating temperatures resulted in relatively poor hot ductility, while lower temperatures improved the ductility. In addition, the alloy composition and the existence of preformed precipitates were found to affect the hot ductility.

STEEL RESEARCH INTERNATIONAL (2023)

Article Materials Science, Multidisciplinary

High-density nanoprecipitates and phase reversion via maraging enable ultrastrong yet strain-hardenable medium-entropy alloy

Hyeonseok Kwon, Praveen Sathiyamoorthi, Manogna Karthik Gangaraju, Alireza Zargaran, Jaemin Wang, Yoon-Uk Heo, Stefanus Harjo, Wu Gong, Byeong-Joo Lee, Hyoung Seop Kim

Summary: In this work, a novel Fe-based medium-entropy alloy was designed based on the characteristics of maraging steels. By a single-step aging at 650 celcius for 10 min, the alloy exhibited microstructures consisting of high-density nanoprecipitates and reverted FCC phase, resulting in ultrahigh yield strength and good ductility.

ACTA MATERIALIA (2023)

Article Chemistry, Physical

Cryogenic tensile behavior of laser additive manufactured CoCrFeMnNi high entropy alloys

Eun Seong Kim, K. R. Ramkumar, G. M. Karthik, Sang Guk Jeong, Soung Yeoul Ahn, Praveen Sathiyamoorthi, Hyojin Park, Yoon-Uk Heo, Hyoung Seop Kim

Summary: In this study, the microstructural evolution, tensile properties, and deformation behavior of additively manufactured equiatomic CoCrFeMnNi high entropy alloy (HEA) were investigated at a cryogenic temperature of 77 K. The results showed that the HEA processed by direct energy deposition (DED) exhibited excellent strength and ductility at 77 K, with exceptional strain hardening, compared to the laser powder bed fusion (LPBF) and wrought samples. The formation of deformation twinning in addition to dislocation slip was observed as the deformation mechanism at 77 K.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Nanoscience & Nanotechnology

Synergy of tensile strength-ductility in IN718/CoCrFeMnNi/IN718 multi-material processed by powder high-pressure torsion and annealing

Gang Hee Gu, Yoon-Uk Heo, Hyeonseok Kwon, Soung Yeoul Ahn, Sujung Son, Peyman Asghari-Rad, Hyoung Seop Kim

Summary: Materials manufactured through conventional powder metallurgy techniques often have inferior tensile properties. However, a recently developed cold-consolidation technique using powder high-pressure torsion has produced well-manufactured structures with ultra-high tensile properties. In this study, the technique was used to fabricate a multi-material Inconel 718/CoCrFeMnNi/Inconel 718 layered structure, which exhibited superior tensile properties compared to monolithic systems. These findings demonstrate the potential of the cold-consolidation technique to manufacture multi-layered and gradient multi-functional structures with excellent mechanical response under tensile stress.

SCRIPTA MATERIALIA (2023)

Article Nanoscience & Nanotechnology

Superior gradient heterostructured alloys fabricated by laser powder bed fusion via annealing and ultrasonic nanocrystal surface modification

Rae Eon Kim, Gangaraju Manogna Karthik, Auezhan Amanov, Yoon-Uk Heo, Sang Guk Jeong, Gang Hee Gu, Hyojin Park, Eun Seong Kim, Do Won Lee, Hyoung Seop Kim

Summary: This study proposes a new strategy to achieve a superior gradient structure in 316L stainless steel fabricated by laser powder bed fusion (LPBF) through annealing and ultrasonic nanocrystal surface modification (UNSM). The post-LPBF annealing treatment disrupts the cellular dislocation structure, resulting in optimized materials for a gradient structure. The resulting gradient structure after UNSM treatment has a thicker gradient layer with significant strain partitioning between domains, leading to superior strength-ductility synergy compared to LPBF-UNSM samples.

SCRIPTA MATERIALIA (2023)

Article Materials Science, Multidisciplinary

Direct observation of the ledge-typed twin boundary in a martensitic steel

T. T. T. Trang, Dongwon Lee, Yoon-Uk Heo

Summary: This study provides a detailed investigation of the twin structure in martensitic steels, clarifying the existence of ledge-typed twin boundaries at the {112} twin boundaries. The ledges occur on {110} planes and exhibit a gradual transition from the primary (112) twin plane to secondary twin planes (011) and (110).

ACTA MATERIALIA (2023)

Article Chemistry, Physical

Performance of MgB2 superconducting wire fabricated with non- identical Mg particles

Minoru Maeda, Akiyoshi Matsumoto, Gen Nishijima, Yoon-Uk Heo, Seungyong Hahn, Sangjin Lee, Seyong Choi, Jung Ho Kim

Summary: In this study, the researchers proposed a method of regulating porous properties using magnesium powder blending. Through a detailed investigation, they found a significant correlation between various particle parameters, impurities, superconducting transition temperature, and current carrying capacity, with the porous properties. The blending of raw powders with spherical shape allowed for tuning of morphological structures and crystallinities inside the cores of the MgB2 superconducting wires, resulting in superior superconducting properties. This finding provides valuable insights for the widespread use and application of superconducting materials.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Materials Science, Multidisciplinary

Unprecedented bake hardening responses of interstitial high-entropy alloy by synergistic effect with lattice distortion

Gang Hee Gu, Hyeonseok Kwon, Yongju Kim, Farahnaz Haftlang, Yoon-Uk Heo, Hyoung Seop Kim

Summary: Carbon-added equi-atomic CoCrFeMnNi high-entropy alloys exhibit bake hardening effect and show better performance compared to conventional bake-hardenable materials, providing possibilities for the industrialization of various interstitial HEA systems as well as carbon-added CoCrFeMnNi HEAs.

MATERIALS & DESIGN (2023)

Article Nanoscience & Nanotechnology

Effect of cooling rate on the final microstructure and tensile property in an Fe-Mn-Si-C-based multiphase TRIP steel

Chang-Gon Jeong, T. T. T. Trang, Youngyun Woo, Eun Yoo Yoon, Youngseon Lee, Yoon- Uk Heo

Summary: The effect of cooling rate on the microstructure and tensile properties of multiphase steel was investigated. Increasing the cooling rate significantly improved the tensile properties without sacrificing elongation, which was attributed to the increased fraction of bainite. All specimens exhibited similar fraction and mechanical stability of gamma.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2023)

Review Microscopy

Transmission electron microscopy study on the phase transformation of metastable precipitates to stable phases

T. T. T. Trang, Yoon-Uk Heo

Summary: Nanosized precipitates are crucial for strengthening metallic alloys. The initial metastable precipitates in these alloys undergo a phase transition to stable phases during heat treatment, which can be studied using a transmission electron microscope.

MICROSCOPY (2023)

Article Nanoscience & Nanotechnology

Cell boundary engineering of ferrous medium-entropy alloy fabricated by laser powder bed fusion

Jeong Min Park, Hyeonseok Kwon, Jungho Choe, Kyung Tae Kim, Ji-Hun Yu, Yoon-Uk Heo, Hyoung Seop Kim

Summary: This study presents a guideline for alloy design in additive manufacturing, aiming to produce high-quality products with excellent mechanical performance by utilizing the unique segregation engineering of LPBF-driven microstructures. Mo-doping enhances the strength and ductility of ferrous medium-entropy alloys.

SCRIPTA MATERIALIA (2023)

Article Materials Science, Multidisciplinary

Transmission electron microscopy of the rapid solidification microstructure evolution and solidification interface velocity determination in hypereutectic Al-20at.%Cu after laser melting

Y. Liu, K. Zweiacker, C. Liu, J. T. McKeown, J. M. K. Wiezorek

Summary: The evolution of rapid solidification microstructure and solidification interface velocity of hypereutectic Al-20at.%Cu alloy after laser melting has been studied experimentally. It was found that the formation of microstructure was dominated by eutectic, alpha-cell, and banded morphology grains, and the growth modes changed with increasing interface velocity.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Mechanisms for high creep resistance in alumina forming austenitic (AFA) alloys

Bharat Gwalani, Julian Escobar, Miao Song, Jonova Thomas, Joshua Silverstein, Andrew Chihpin Chuang, Dileep Singh, Michael P. Brady, Yukinori Yamamoto, Thomas R. Watkins, Arun Devaraj

Summary: Castable alumina forming austenitic alloys exhibit superior creep life and oxidation resistance at high temperatures. This study reveals the mechanism behind the enhanced creep performance of these alloys by suppressing primary carbide formation and offers a promising alloy design strategy for high-temperature applications.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Achieving atomically flat copper surface: Formation of mono-atomic steps and associated strain energy mechanisms

Jian Song, Qi Zhang, Songsong Yao, Kunming Yang, Houyu Ma, Jiamiao Ni, Boan Zhong, Yue Liu, Jian Wang, Tongxiang Fan

Summary: Recent studies have shown that achieving an atomically flat surface for metals can greatly improve their oxidation resistance and enhance their electronic-optical applications. Researchers have explored the use of graphene as a covering layer to achieve atomically flat surfaces. They found that high-temperature deposited graphene on copper surfaces formed mono-atomic steps, while annealed copper and transferred graphene on copper interfaces formed multi-atomic steps.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Modeling and measurements of creep deformation in laser-melted Al-Ti-Zr alloys with bimodal grain size

Jennifer A. Glerum, Jon-Erik Mogonye, David C. Dunand

Summary: Elemental powders of Al, Ti, Sc, and Zr are blended and processed via laser powder-bed fusion to create binary and ternary alloys. The microstructural analysis and mechanical testing show that the addition of Ti results in the formation of primary precipitates, while the addition of Sc and Zr leads to the formation of fine grain bands. The Al-0.25Ti-0.25Zr alloy exhibits comparable strain rates to Al-0.5Zr at low stresses, but significantly higher strain rates at higher stresses during compressive creep testing. Finite element modeling suggests that the connectivity of coarse and fine grain regions is a critical factor affecting the creep resistance of the alloys.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Characterizing stable nanocrystalline Cu-Ta behavior and failure dynamics under extremes of strain rate, strain, temperature and pressure by modified dynamic tensile extrusion

P. Jannotti, B. C. Hornbuckle, J. T. Lloyd, N. Lorenzo, M. Aniska, T. L. Luckenbaugh, A. J. Roberts, A. Giri, K. A. Darling

Summary: This work characterizes the thermo-mechanical behavior of bulk nanocrystalline Cu-Ta alloys under extreme conditions. The experiments reveal that the alloys exhibit unique mechanical properties, behaving differently from conventional nanocrystalline Cu. They do not undergo grain coarsening during extrusion and exhibit behavior similar to coarse-grained Cu.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Phase-dependent microstructure modification leads to high thermoelectric performance in n-type layered SnSe2

Yiqing Wei, Jingwei Li, Daliang Zhang, Bin Zhang, Zizhen Zhou, Guang Han, Guoyu Wang, Carmelo Prestipino, Pierric Lemoine, Emmanuel Guilmeau, Xu Lu, Xiaoyuan Zhou

Summary: This study proposes a new strategy to modify microstructure by phase regulation, which can simultaneously enhance carrier mobility and reduce lattice thermal conductivity. The addition of Cu in layered SnSe2 induces a phase transition that leads to increased grain size and reduced stacking fault density, resulting in improved carrier mobility and lower lattice thermal conductivity.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Selective oxidation and nickel enrichment hinders the repassivation kinetics of multi-principal element alloy surfaces

Jia Chen, Zhengyu Zhang, Eitan Hershkovitz, Jonathan Poplawsky, Raja Shekar Bhupal Dandu, Chang-Yu Hung, Wenbo Wang, Yi Yao, Lin Li, Hongliang Xin, Honggyu Kim, Wenjun Cai

Summary: In this study, the structural origin of the pH-dependent repassivation mechanisms in multi-principal element alloys (MPEA) was investigated using surface characterization and computational simulations. It was found that selective oxidation in acidic to neutral solutions leads to enhanced nickel enrichment on the surface, resulting in reduced repassivation capability and corrosion resistance.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Rate-dependent transition of dislocation mechanisms in a magnesium alloy

X. Y. Xu, C. P. Huang, H. Y. Wang, Y. Z. Li, M. X. Huang

Summary: The limited slip systems of magnesium (Mg) and its alloys hinder their wide applications. By conducting tensile straining experiments, researchers discovered a rate-dependent transition in the dislocation mechanisms of Mg alloys. At high strain rates, glissile dislocations dominate, while easy-glide dislocations dominate at low strain rates. Abundant glissile dislocations do not necessarily improve ductility.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

The effect of temperature on detwinning and mechanical properties of face-centered cubic deformation twins

M. S. Szczerba, M. J. Szczerba

Summary: Inverse temperature dependences of the detwinning stress were observed in face-centered cubic deformation twins in Cu-8at.%Al alloy. The detwinning stress increased with temperature when the pi detwinning mode was involved, but decreased when the pi/3 mode was involved. The dual effect of temperature on the detwinning stress was due to the reduction of internal stresses pre-existing within the deformation twins. The complete reduction of internal stresses at about 530 degrees C led to the equivalence of the critical stresses of different detwinning modes and a decrease in the yield stress anisotropy of the twin/matrix structure.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Nature of the electric double layer to modulate the electrochemical behaviors of Fe2O3 electrode

Taowen Dong, Tingting Qin, Wei Zhang, Yaowen Zhang, Zhuoran Feng, Yuxiang Gao, Zhongyu Pan, Zixiang Xia, Yan Wang, Chunming Yang, Peng Wang, Weitao Zheng

Summary: The interaction between the electrode and the electric double layer (EDL) significantly influences the energy storage mechanism. By studying the popular alpha-Fe2O3 electrode and the EDL interaction, we find that the energy storage mechanism of the electrode can be controlled by modulating the EDL.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Grain scale bursts of plasticity in Mg-4Zn via high energy X-rays: Towards twin observation in real-time

Matthew R. Barnett, Jun Wang, Sitarama R. Kada, Alban de Vaucorbeil, Andrew Stevenson, Marc Fivel, Peter A. Lynch

Summary: The elastic-plastic transition in magnesium alloy Mg-4.5Zn exhibits bursts of deformation, which are characterized by sudden changes in grain orientation. These bursts occur in a coordinated manner among nearby grains, with the highest burst rate observed at the onset of full plasticity. The most significant burst events are associated with twinning, supported by the observation of twinned structures using electron microscopy. The bursts are often preceded and followed by a stasis in peak movement, indicating a certain "birth size" for twins upon formation and subsequent growth at a later stage.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Atomistic simulations and machine learning of solute grain boundary segregation in Mg alloys at finite temperatures

Vaidehi Menon, Sambit Das, Vikram Gavini, Liang Qi

Summary: Understanding solute segregation thermodynamics is crucial for investigating grain boundary properties. The spectral approach and thermodynamic integration methods can be used to predict solute segregation behavior at grain boundaries and compare with experimental observations, thus aiding in alloy design and performance control.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Integrating abnormal thermal expansion and ultralow thermal conductivity into (Cd,Ni)2Re2O7 via synergy of local structure distortion and soft acoustic phonons

Feiyu Qin, Lei Hu, Yingcai Zhu, Yuki Sakai, Shogo Kawaguchi, Akihiko Machida, Tetsu Watanuki, Yue-Wen Fang, Jun Sun, Xiangdong Ding, Masaki Azuma

Summary: This study reports on the negative and zero thermal expansion properties of Cd2Re2O7 and Cd1.95Ni0.05Re2O7 materials, along with their ultra-low thermal conductivity. Through investigations of their structures and phonon calculations, the synergistic effect of local structure distortion and soft phonons is revealed as the key to achieving these distinctive properties.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Semi-automatic miniature specimen testing method to characterize the plasticity and fracture properties of metals

Thomas Beerli, Christian C. Roth, Dirk Mohr

Summary: A novel testing system for miniature specimens is designed to characterize the plastic response of materials for which conventional full-size specimens cannot be extracted. The system has an automated operation process, which reduces the damage to specimens caused by manual handling and improves the stability of the test results. The experiments show that the miniature specimens extracted from stainless steel and aluminum have high reproducibility, and the results are consistent with those of conventional-sized specimens. A correction procedure is provided to consider the influence of surface roughness and heat-affected zone caused by wire EDM.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

The effect of microstructure and film composition on the mechanical properties of linear antenna CVD diamond thin films

Rani Mary Joy, Paulius Pobedinskas, Nina Baule, Shengyuan Bai, Daen Jannis, Nicolas Gauquelin, Marie-Amandine Pinault-Thaury, Francois Jomard, Kamatchi Jothiramalingam Sankaran, Rozita Rouzbahani, Fernando Lloret, Derese Desta, Jan D'Haen, Johan Verbeeck, Michael Frank Becker, Ken Haenen

Summary: This study investigates the influence of film microstructure and composition on the Young's modulus and residual stress in nanocrystalline diamond thin films. The results provide insights into the mechanical properties and intrinsic stress sources of these films, and demonstrate the potential for producing high-quality nanocrystalline diamond films under certain conditions.

ACTA MATERIALIA (2024)