Growth of austenite from as-quenched martensite during intercritical annealing in an Fe-0.1C-3Mn-1.5Si alloy

The growth of austenite from as-quenched martensite during intercritical annealing was studied in a quaternary Fe-0.1C-3Mn-1.5Si alloy. Fine austenite grains either grew from interlath-retained austenite films or were newly nucleated at lath and martensite packet boundaries. Both types grew to a size comparable to the width of the martensite lath. It was found both metallographically and by dilatometry that the austenite grew to an amount in excess of the volume fraction at final equilibrium. Simulation by DICTRA, which assumed local equilibrium at the alpha/gamma boundary, confirmed that the development of austenite is composed of three stages: initial negligible-partitioning growth controlled by rapid carbon diffusion in ferrite, which is gradually replaced by carbon diffusion in austenite; intermediate slow growth, controlled by diffusion of Mn and/or Si in ferrite; and a final stage controlled by diffusion of substitutional elements in austenite for final equilibration, which may result in the shrinkage of austenite. The formation of austenite in excess of the equilibrium amount is considered to occur due to very slow substitutional diffusion in the growing austenite compared to the boundary migration. (c) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.