4.7 Article

Defect microstructure in heavy-ion-bombarded (0001) ZnO

期刊

ACTA MATERIALIA
卷 60, 期 17, 页码 6086-6090

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2012.07.046

关键词

Intermediate defect peak; ZnO surface; Ion implantation; ZnO; Radiation damage

资金

  1. US DOE by LLNL [DE-AC52-07NA27344]
  2. NSF [0846835]
  3. Div Of Civil, Mechanical, & Manufact Inn
  4. Directorate For Engineering [0846835] Funding Source: National Science Foundation

向作者/读者索取更多资源

Radiation defects in oxides are complex and remain poorly understood. Here, we use transmission electron microscopy to study ZnO crystals bombarded at room temperature with heavy ions (500 keV Xe). Results reveal that the damage evolution proceeds via the formation of a band of cavities centered similar to 7 nm from the sample surface. With further irradiation, a layered structure is formed, with alternating near-stoichiometric and Zn-rich layers. The anomalous intermediate peak and step in ion channeling spectra are attributed to a Zn-rich defect band and an interface between stoichiometric and Zn-rich layers, respectively. To explain these observations, we propose a damage build-up scenario involving vacancy clustering, loss of 0 from the surface, and peculiarities of point-defect transport through a Zn-rich defect band toward the surface. (C) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

Size- and concentration-dependent Eu2+/Eu3+ mixed luminescent characteristics of rare-earth-doped CaF2 nanoparticles and their monolithic epoxy nanocomposites

Gibin George, Jacob Hayes, Candyce N. Collins, Jason E. Davis, Lei Yu, Yulin Lin, Jianguo Wen, Daryush Ila, Zhiping Luo

Summary: This study investigates the photoluminescence and cathodoluminescence characteristics of rare-earth-doped CaF2 nanoparticles and their composite monoliths with epoxy. The results show that the luminescence intensity increases as the particle size decreases for single-doped particles, but decreases for codoped particles. Additionally, Eu2+- and Tb3+-codoped CaF2 nanoparticles exhibit red emission.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Materials Science, Multidisciplinary

Recent trends in metallic fast reactor fuels research

Assel Aitkaliyeva

Summary: Metallic nuclear fuels have been extensively studied for over 60 years, showing distinctive irradiation behaviors compared to oxide fuels. Current gaps in understanding and recommendations for future research direction are identified for metallic U-Zr and U-Pu-Zr fuels. This review highlights key aspects of metallic fuel irradiation behaviors and points out areas for further research based on recent studies.

JOURNAL OF NUCLEAR MATERIALS (2022)

Article Materials Science, Multidisciplinary

High burnup structure formation in U-Mo fuels

Charlyne A. Smith, Sudipta Biswas, Brandon D. Miller, Boopathy Kombaiah, David Frazer, Dennis D. Keiser, Assel Aitkaliyeva

Summary: This study used electron microscopy techniques and phase field modeling to investigate the mechanisms responsible for developing the high burnup structure in U-Mo fuels. The results show that grain subdivision is primarily initiated by polygonization, but dynamic recrystallization also occurs with increasing fission densities.

JOURNAL OF NUCLEAR MATERIALS (2022)

Article Nanoscience & Nanotechnology

Photo-exfoliation of MoS2 quantum dots from nanosheets: an in situ transmission electron microscopy study

Kory Burns, Benjamin Bischoff, Christopher M. Barr, Khalid Hattar, Assel Aitkaliyeva

Summary: By utilizing infrared laser irradiation of free-standing MoS2 flakes in TEM, solid-state multi-level photoexfoliation of transition metal dichalcogenide quantum dots (QDs) is achieved, leading to high yield production. These findings provide an environmentally friendly synthesis method for fabricating QDs for potential applications in biomedicine, optoelectronics, and fluorescence sensing.

NANOTECHNOLOGY (2022)

Article Crystallography

Thermal Stability and Radiation Tolerance of Lanthanide-Doped Cerium Oxide Nanocubes

Kory Burns, Paris C. Reuel, Fernando Guerrero, Eric Lang, Ping Lu, Assel Aitkaliyeva, Khalid Hattar, Timothy J. Boyle

Summary: The thermal and radiation stability of lanthanide-doped ceria nanoparticles were investigated, showing good thermal stability but tendency for amorphization under heavy ion irradiation. The impact of cation dopants on final nanoparticle properties was explored.

CRYSTALS (2021)

Article Materials Science, Multidisciplinary

Rare-earth-doped electrospun scheelite CaWO4 nanofibers with excitation-dependent photoluminescence and high-linearity cathodoluminescence for ratiometric UV wavelength and radiation sensors

Gibin George, Navadeep Shrivastava, Tamela L. Moore, Caressia S. Edwards, Yulin Lin, Jianguo Wen, Zhiping Luo

Summary: In this study, high-aspect-ratio AWO(4) (A = Ba, Ca, Pb and Sr) nanofibers doped with Tb and Eu ions were synthesized and their performance in UV light detection was compared. The CaWO4:5Tb-5Eu nanofibers exhibited strong photoluminescence and cathodoluminescence emissions, making them a potential fluorescent probe for UV wavelength detection. However, similar results were not observed in nanofibers of other AWO(4) compounds. Additionally, the CL intensities from CaWO4:5Tb-5Eu nanofibers showed highly linear dependences on applied voltage and current, suggesting their potential use in radiation detection.

OPTICAL MATERIALS (2022)

Article Materials Science, Multidisciplinary

Luminescence from Self-Trapped Excitons and Energy Transfers in Vacancy-Ordered Hexagonal Halide Perovskite Cs2HfF6 Doped with Rare Earths for Radiation Detection

Menuka Adhikari, Navadeep Shrivastava, Starfari T. McClain, Chandra M. Adhikari, Burak Guzelturk, Rabi Khanal, Bhoj Gautam, Zhiping Luo

Summary: The halide Cs2HfF6 (CHF) possesses higher mass density and chemical stability for radiation detection compared to halides Cs2HfX6. Luminescence properties and energy transfer mechanisms of rare-earth-doped CHF materials are studied. Codoped CHF material shows stable emission and higher sensitivity to radiation energy.

ADVANCED OPTICAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Compositional Effects of Additively Manufactured Refractory High-Entropy Alloys under High-Energy Helium Irradiation

Eric Lang, Kory Burns, Yongqiang Wang, Paul G. Kotula, Andrew B. Kustas, Sal Rodriguez, Assel Aitkaliyeva, Khalid Hattar

Summary: High-Entropy Alloys (HEAs) are proposed as materials for extreme environments, but the effects of radiation on their performance are not well understood. In this study, the response of additively manufactured refractory high-entropy alloys (RHEAs) to helium ion bombardment is investigated, revealing the interplay between alloy composition and helium bubble size and density.

NANOMATERIALS (2022)

Article Materials Science, Multidisciplinary

TEM-based phase characterization of U-19Pu-10Zr irradiated in ATR

Thaddeus Rahn, Brandon D. Miller, Luca Capriotti, Assel Aitkaliyeva

Summary: This article presents the microstructural examination of irradiated U-19Pu-10Zr fuel using selective area electron diffraction analysis. The results reveal the crystallographic information on the identified phases and highlight the importance of crystal structure in phase identification.

MRS BULLETIN (2023)

Article Chemistry, Multidisciplinary

Material Properties of Traditional Handmade Paper Samples Fabricated from Cellulosic Fiber of Lokta Bushes

Girja Mani Aryal, Krishna Prasad Kandel, Ram Kumar Bhattarai, Basant Giri, Menuka Adhikari, Alisha Ware, Shubo Han, Gibin George, Zhiping Luo, Bhoj Raj Gautam, Bhanu Bhakta Neupane

Summary: In this study, multiple material properties of handmade Lokta paper from Nepal were measured and analyzed. The findings revealed that the papers are lightweight with intermediate to high strength, and the tensile strength is significantly higher along the length direction. Features of cellulose, hemicellulose, and lignin were observed in FTIR spectra, and crystalline and amorphous phases were identified in XRD data. Electron microscopy images showed a cross-linked network of fibers contributing to strength and durability.

ACS OMEGA (2022)

Article Materials Science, Multidisciplinary

The complex structural and chemical nature of monolithic U-10Mo fuel and Zr barrier layer

C. M. Barr, E. Lang, K. Burns, P. Price, B. D. Miller, D. D. Keiser, A. Aitkaliyeva, K. Hattar

Summary: Nanoscale microstructural characterization of a U-10Mo/Zr barrier layer monolithic fuel plate was conducted using advanced transmission electron microscopy techniques to evaluate the microstructural changes after high burn-up. The study investigated the evolution of gas bubble superlattice, grain restructuring, and Zr inter-action layer through detailed electron microscopy characterization. The results revealed that the ultra-fine grains in irradiated U-10Mo fuel undergo restructuring and are separated by high angle grain boundaries at a burn-up of 4.42 x 10 21 fissions/cm3. Advanced chemical analysis and multi-variable statistical analysis also showed spatial clustering of solid fission product precipitates. Additionally, a newly observed porous nanocrystalline Zr region in the barrier layer was characterized. This work provides important insights into the grain subdivision and restructuring process in neutron-irradiated U-10Mo fuel using advanced microscopy techniques.

JOURNAL OF NUCLEAR MATERIALS (2023)

Article Materials Science, Multidisciplinary

Three-dimensional microstructural characterization of FBR MOX fuel and the contribution of microstructural features to the thermal conductivity of the fuel

Casey McKinney, Floyd Hilty, Daniel Murray, Narayan Poudel, Fabiola Cappia, Tsvetoslav Pavlov, Assel Aitkaliyeva

Summary: The combination of microstructural characterization, property measurements, and phase field modeling was used to investigate the irradiation of FBR MOX fuel. The presence of grey phase in the central region depends on the nucleation of five metal precipitates. In addition, metal precipitates do not diffuse out of the mid-radial region once formed, and the size of Pd-Te precipitates is determined by the porosity in the region. Thermal conductivity measurements were conducted and correlated with the observed microstructure trend.

JOURNAL OF NUCLEAR MATERIALS (2022)

Article Nanoscience & Nanotechnology

Materials for extreme environments

Suhas Eswarappa Prameela, Tresa M. Pollock, Dierk Raabe, Marc Andre Meyers, Assel Aitkaliyeva, Kerri-Lee Chintersingh, Zachary C. Cordero, Lori Graham-Brady

Summary: This viewpoint article discusses the importance of materials for extreme environments, and presents insights from experts in different fields regarding the most exciting advances, opportunities, and bottlenecks.

NATURE REVIEWS MATERIALS (2023)

Article Chemistry, Multidisciplinary

Tailoring the Angular Mismatch in MoS2 Homobilayers through Deformation Fields

Kory Burns, Anne Marie Z. Tan, Jordan A. A. Hachtel, Anikeya Aditya, Nitish Baradwaj, Ankit Mishra, Thomas Linker, Aiichiro Nakano, Rajiv Kalia, Eric J. J. Lang, Ryan Schoell, Richard G. G. Hennig, Khalid Hattar, Assel Aitkaliyeva

Summary: Ultrathin MoS2 shows remarkable characteristics at the atomic scale and is resistant to weak external stimuli. Ion beam modification can selectively adjust the size, concentration, and morphology of defects in 2D materials. By combining experiments, calculations, simulations, and transfer learning, this study demonstrates that irradiation-induced defects can create a rotation-dependent moire pattern and surface acoustic waves in vertically stacked homobilayers of MoS2. The direct correlation between stress and lattice disorder is also demonstrated. This research sheds light on the engineering of defects to tailor the angular mismatch in van der Waals solids.
Article Materials Science, Multidisciplinary

Electrospun porous La-Sr-Co-Ni-O nanofibers for highly sensitive non-enzymatic glucose detection

Kasci D. Pelucarte, Tashi A. Hatchell, Gibin George, Sivasankara Rao Ede, Menuka Adhikari, Yulin Lin, Jianguo Wen, Zhiping Luo, Shubo Han

Summary: In this study, porous La-Sr-Co-Ni-O nanofibers with a perovskite structure were successfully prepared and utilized to develop a nonenzymatic electrochemical glucose biosensor. The biosensor exhibited high sensitivity and excellent stability towards glucose, while showing low interference response to other biomolecules. This research has great potential for practical applications in clinical testing.

MATERIALS ADVANCES (2022)

Article Materials Science, Multidisciplinary

Transmission electron microscopy of the rapid solidification microstructure evolution and solidification interface velocity determination in hypereutectic Al-20at.%Cu after laser melting

Y. Liu, K. Zweiacker, C. Liu, J. T. McKeown, J. M. K. Wiezorek

Summary: The evolution of rapid solidification microstructure and solidification interface velocity of hypereutectic Al-20at.%Cu alloy after laser melting has been studied experimentally. It was found that the formation of microstructure was dominated by eutectic, alpha-cell, and banded morphology grains, and the growth modes changed with increasing interface velocity.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Mechanisms for high creep resistance in alumina forming austenitic (AFA) alloys

Bharat Gwalani, Julian Escobar, Miao Song, Jonova Thomas, Joshua Silverstein, Andrew Chihpin Chuang, Dileep Singh, Michael P. Brady, Yukinori Yamamoto, Thomas R. Watkins, Arun Devaraj

Summary: Castable alumina forming austenitic alloys exhibit superior creep life and oxidation resistance at high temperatures. This study reveals the mechanism behind the enhanced creep performance of these alloys by suppressing primary carbide formation and offers a promising alloy design strategy for high-temperature applications.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Achieving atomically flat copper surface: Formation of mono-atomic steps and associated strain energy mechanisms

Jian Song, Qi Zhang, Songsong Yao, Kunming Yang, Houyu Ma, Jiamiao Ni, Boan Zhong, Yue Liu, Jian Wang, Tongxiang Fan

Summary: Recent studies have shown that achieving an atomically flat surface for metals can greatly improve their oxidation resistance and enhance their electronic-optical applications. Researchers have explored the use of graphene as a covering layer to achieve atomically flat surfaces. They found that high-temperature deposited graphene on copper surfaces formed mono-atomic steps, while annealed copper and transferred graphene on copper interfaces formed multi-atomic steps.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Modeling and measurements of creep deformation in laser-melted Al-Ti-Zr alloys with bimodal grain size

Jennifer A. Glerum, Jon-Erik Mogonye, David C. Dunand

Summary: Elemental powders of Al, Ti, Sc, and Zr are blended and processed via laser powder-bed fusion to create binary and ternary alloys. The microstructural analysis and mechanical testing show that the addition of Ti results in the formation of primary precipitates, while the addition of Sc and Zr leads to the formation of fine grain bands. The Al-0.25Ti-0.25Zr alloy exhibits comparable strain rates to Al-0.5Zr at low stresses, but significantly higher strain rates at higher stresses during compressive creep testing. Finite element modeling suggests that the connectivity of coarse and fine grain regions is a critical factor affecting the creep resistance of the alloys.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Characterizing stable nanocrystalline Cu-Ta behavior and failure dynamics under extremes of strain rate, strain, temperature and pressure by modified dynamic tensile extrusion

P. Jannotti, B. C. Hornbuckle, J. T. Lloyd, N. Lorenzo, M. Aniska, T. L. Luckenbaugh, A. J. Roberts, A. Giri, K. A. Darling

Summary: This work characterizes the thermo-mechanical behavior of bulk nanocrystalline Cu-Ta alloys under extreme conditions. The experiments reveal that the alloys exhibit unique mechanical properties, behaving differently from conventional nanocrystalline Cu. They do not undergo grain coarsening during extrusion and exhibit behavior similar to coarse-grained Cu.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Phase-dependent microstructure modification leads to high thermoelectric performance in n-type layered SnSe2

Yiqing Wei, Jingwei Li, Daliang Zhang, Bin Zhang, Zizhen Zhou, Guang Han, Guoyu Wang, Carmelo Prestipino, Pierric Lemoine, Emmanuel Guilmeau, Xu Lu, Xiaoyuan Zhou

Summary: This study proposes a new strategy to modify microstructure by phase regulation, which can simultaneously enhance carrier mobility and reduce lattice thermal conductivity. The addition of Cu in layered SnSe2 induces a phase transition that leads to increased grain size and reduced stacking fault density, resulting in improved carrier mobility and lower lattice thermal conductivity.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Selective oxidation and nickel enrichment hinders the repassivation kinetics of multi-principal element alloy surfaces

Jia Chen, Zhengyu Zhang, Eitan Hershkovitz, Jonathan Poplawsky, Raja Shekar Bhupal Dandu, Chang-Yu Hung, Wenbo Wang, Yi Yao, Lin Li, Hongliang Xin, Honggyu Kim, Wenjun Cai

Summary: In this study, the structural origin of the pH-dependent repassivation mechanisms in multi-principal element alloys (MPEA) was investigated using surface characterization and computational simulations. It was found that selective oxidation in acidic to neutral solutions leads to enhanced nickel enrichment on the surface, resulting in reduced repassivation capability and corrosion resistance.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Rate-dependent transition of dislocation mechanisms in a magnesium alloy

X. Y. Xu, C. P. Huang, H. Y. Wang, Y. Z. Li, M. X. Huang

Summary: The limited slip systems of magnesium (Mg) and its alloys hinder their wide applications. By conducting tensile straining experiments, researchers discovered a rate-dependent transition in the dislocation mechanisms of Mg alloys. At high strain rates, glissile dislocations dominate, while easy-glide dislocations dominate at low strain rates. Abundant glissile dislocations do not necessarily improve ductility.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

The effect of temperature on detwinning and mechanical properties of face-centered cubic deformation twins

M. S. Szczerba, M. J. Szczerba

Summary: Inverse temperature dependences of the detwinning stress were observed in face-centered cubic deformation twins in Cu-8at.%Al alloy. The detwinning stress increased with temperature when the pi detwinning mode was involved, but decreased when the pi/3 mode was involved. The dual effect of temperature on the detwinning stress was due to the reduction of internal stresses pre-existing within the deformation twins. The complete reduction of internal stresses at about 530 degrees C led to the equivalence of the critical stresses of different detwinning modes and a decrease in the yield stress anisotropy of the twin/matrix structure.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Nature of the electric double layer to modulate the electrochemical behaviors of Fe2O3 electrode

Taowen Dong, Tingting Qin, Wei Zhang, Yaowen Zhang, Zhuoran Feng, Yuxiang Gao, Zhongyu Pan, Zixiang Xia, Yan Wang, Chunming Yang, Peng Wang, Weitao Zheng

Summary: The interaction between the electrode and the electric double layer (EDL) significantly influences the energy storage mechanism. By studying the popular alpha-Fe2O3 electrode and the EDL interaction, we find that the energy storage mechanism of the electrode can be controlled by modulating the EDL.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Grain scale bursts of plasticity in Mg-4Zn via high energy X-rays: Towards twin observation in real-time

Matthew R. Barnett, Jun Wang, Sitarama R. Kada, Alban de Vaucorbeil, Andrew Stevenson, Marc Fivel, Peter A. Lynch

Summary: The elastic-plastic transition in magnesium alloy Mg-4.5Zn exhibits bursts of deformation, which are characterized by sudden changes in grain orientation. These bursts occur in a coordinated manner among nearby grains, with the highest burst rate observed at the onset of full plasticity. The most significant burst events are associated with twinning, supported by the observation of twinned structures using electron microscopy. The bursts are often preceded and followed by a stasis in peak movement, indicating a certain "birth size" for twins upon formation and subsequent growth at a later stage.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Atomistic simulations and machine learning of solute grain boundary segregation in Mg alloys at finite temperatures

Vaidehi Menon, Sambit Das, Vikram Gavini, Liang Qi

Summary: Understanding solute segregation thermodynamics is crucial for investigating grain boundary properties. The spectral approach and thermodynamic integration methods can be used to predict solute segregation behavior at grain boundaries and compare with experimental observations, thus aiding in alloy design and performance control.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Integrating abnormal thermal expansion and ultralow thermal conductivity into (Cd,Ni)2Re2O7 via synergy of local structure distortion and soft acoustic phonons

Feiyu Qin, Lei Hu, Yingcai Zhu, Yuki Sakai, Shogo Kawaguchi, Akihiko Machida, Tetsu Watanuki, Yue-Wen Fang, Jun Sun, Xiangdong Ding, Masaki Azuma

Summary: This study reports on the negative and zero thermal expansion properties of Cd2Re2O7 and Cd1.95Ni0.05Re2O7 materials, along with their ultra-low thermal conductivity. Through investigations of their structures and phonon calculations, the synergistic effect of local structure distortion and soft phonons is revealed as the key to achieving these distinctive properties.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

Semi-automatic miniature specimen testing method to characterize the plasticity and fracture properties of metals

Thomas Beerli, Christian C. Roth, Dirk Mohr

Summary: A novel testing system for miniature specimens is designed to characterize the plastic response of materials for which conventional full-size specimens cannot be extracted. The system has an automated operation process, which reduces the damage to specimens caused by manual handling and improves the stability of the test results. The experiments show that the miniature specimens extracted from stainless steel and aluminum have high reproducibility, and the results are consistent with those of conventional-sized specimens. A correction procedure is provided to consider the influence of surface roughness and heat-affected zone caused by wire EDM.

ACTA MATERIALIA (2024)

Article Materials Science, Multidisciplinary

The effect of microstructure and film composition on the mechanical properties of linear antenna CVD diamond thin films

Rani Mary Joy, Paulius Pobedinskas, Nina Baule, Shengyuan Bai, Daen Jannis, Nicolas Gauquelin, Marie-Amandine Pinault-Thaury, Francois Jomard, Kamatchi Jothiramalingam Sankaran, Rozita Rouzbahani, Fernando Lloret, Derese Desta, Jan D'Haen, Johan Verbeeck, Michael Frank Becker, Ken Haenen

Summary: This study investigates the influence of film microstructure and composition on the Young's modulus and residual stress in nanocrystalline diamond thin films. The results provide insights into the mechanical properties and intrinsic stress sources of these films, and demonstrate the potential for producing high-quality nanocrystalline diamond films under certain conditions.

ACTA MATERIALIA (2024)