期刊
INDUSTRIAL CROPS AND PRODUCTS
卷 77, 期 -, 页码 180-189出版社
ELSEVIER
DOI: 10.1016/j.indcrop.2015.08.015
关键词
Cellulose acylation; Kinetics; 1-Allyl-3-methylimidazolium chloride ionic liquid; Imidazole catalysis; Dipolar aprotic solvents; Solvatochromism; Molecular dynamics simulations
资金
- FAPESP (Sao Paulo research Foundation)
- CNPq (National Council for Scientific and Technological Research)
- TWAS (the world academy of sciences)
Observed rate constants (k(obs)) for the imidazole-catalyzed acylation of microcrystalline cellulose by carboxylic acid anhydrides (ethanoic to hexanoic) were calculated from conductivity data. The reaction media consisted of the ionic liquid, IL, 1-allyl-3-methylimidazolium chloride and the molecular solvents, MSs, N,N-dimethylacetamide, DMAc, dimethylsulfoxide, DMSO, and sulfolane, Sulfn. The latter two carry the same dipole (S=O) and have some similar properties. Using FTIR, we showed that the acylating agent is N-acylimidazole. The reaction third order rate constants (k(3)) depend slightly on [IL] because the reactant is cellulose-IL complex. For ethanoic anhydride, values of k(3) decrease in the order: IL-DMSO > IL-DMAc > IL-Sulfn. We analyze this dependence on the nature of the MS by considering the reaction activation parameters; some macroscopic and microscopic properties of the binary solvent mixtures and cellulose solutions therein, and the results of molecular dynamics simulations. Favorable activation enthalpy; lower solution viscosity; larger empirical polarity and basicity, and stronger biopolymer-solvent interactions are responsible for the faster reaction in IL-DMSO, relative to that in IL-Sulfn. The dependence of the values of (k(3)) on the number of carbon atoms in the acyl moiety showed a complex behavior (decrease from C-2 to C-4 and then increase), similar to that observed before, probably because of enthalpy/entropy compensation. (C) 2015 Elsevier B.V. All rights reserved.
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