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Hexakis(thiourea-κS)nickel(II) nitrate: a redetermination

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE (2010)

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ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

卷 66, 期 -, 页码 I57-U68

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WILEY-BLACKWELL

DOI: 10.1107/S1600536810026668

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Crystallography

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Higher Education Commission of Pakistan

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A preliminary X-ray study of the title molecular salt, [Ni(CH4N2S)(6)](NO3)(2), has been reported twice previously, by Maar [Acta Cryst. (1961), 14, 894] and Rodriguez, Cubero, Vega, Morente & Vazquez [Acta Cryst. (1961), 14, 1101], using film methods. We confirm the previous studies, but to modern standards of precision and with all H atoms located. The central Ni atom (site symmetry (1) over bar) of the dication is octahedrally coordinated by six S-bound thiourea molecules. The crystal structure is stabilized by intra- and intermolecular N-H...S and N-H...O hydrogen bonds.

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