期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 54, 期 15, 页码 3754-3760出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie505004k
关键词
-
资金
- Deanship of Academic Research
- University of Jordan
- Royal Scientific Society, Jordan
- Swiss National Science Foundation [206021-128741/1]
- Swiss National Science Foundation (SNF) [206021_128741] Funding Source: Swiss National Science Foundation (SNF)
The present work describes the utilization of high-silica kaolinite for the synthesis of zeolite ZSM-5 With different SiO2/Al2O3 ratios. The new synthetic Method, which involves acid base activation of metakaolinite, is most suitable for the production of high-silica zeolites. The process starts with the conversion of kaolinite to metakaolinite, which is then dealuminated with sulfuric acid with varying concentrations. A relationship between the add concentration and the SiO2/Al2O3 ratio in the final product was established. The dealuminated kaolinite was hydrothermally treated with alkali to obtain phase-pure ZSM-5. The zeolites were characterized by XRF, XRD, SEM, and N-2 physisorption. The sodium form of the zeolite was converted to the add form for application in catalytic dehydration of alcohols. The catalytic activity of the zeolite was tested in the dehydration of 1-phenylethanol into styrene. The results reveal a selective formation of styrene in high yield that teaches up to 95%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据