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Bis[μ-2-(2H-benzotriazol-2-yl)-4-methylphenolato]bis[dimethylaluminium(III)]

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INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536809018492

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  1. National Science Council, Taiwan [NSC97-2113-M-033-005-MY2]
  2. Project of the Specific Research Fields in Chung Yuan Christian University, Taiwan [CYCU-97-CR-CH]

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The title complex, [Al-2(CH3)(4)(C13H10N3O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the molecule and there is a crystallographic inversion centre in this molecule. Each Al atom is pentacoordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal-bipyramidal environment.

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