期刊
ACS APPLIED MATERIALS & INTERFACES
卷 10, 期 39, 页码 33214-33220出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b10620
关键词
zeolite; ITE; nickel-pentaethylenexamine; design synthesis; hydrogenation of CO2
资金
- National Key Research and Development Program of China [2017YFB0702803]
- National Natural Science Foundation of China [91634201, 91545111, 21703203, 21802053, 21720102001]
- China Postdoctoral Science Foundation [2017M611978]
Modern methodologies for synthesizing zeolites typically involve the employment of costly organic structure-directing agents. Herein, we report the design synthesis of aluminosilicate zeolite with ITE structure using an inexpensive nickel amine complex (nickel-pentaethylenexamine) as a novel structure-directing agent. Characterizations including X-ray diffraction, scanning electron microscopy, N-2 sorption isotherms, and Al-27 magic-angle spinning NMR techniques show that the ITE zeolite has high crystallinity, perfect crystals, large surface area, and abundant aluminum species in the framework. More importantly, catalytic tests on the hydrogenation of CO2 into methane show that the Ni-ITE zeolite exhibits better catalytic performance than aluminosilicate-supported and silica-supported nickel catalysts. Obviously, the use of nickel amine complex offers an alternative and facile way to synthesize aluminosilicate zeolites.
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