期刊
ACS APPLIED MATERIALS & INTERFACES
卷 5, 期 4, 页码 1453-1459出版社
AMER CHEMICAL SOC
DOI: 10.1021/am302925s
关键词
plastic ionic crystals; SiO2 nanoparticles; dye-sensitized solar cells; solid-state electrolyte; stability
资金
- Natural Science Foundation of China [21174102, 21274101]
- Natural Science Foundation of Jiangsu Province [BK2011274]
- Program for Scientific Innovation Research of College Graduate in Jiangsu Province [CXZZ11-0103]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
Organic ionic plastic crystal, 1-propyl-1-methylpyrrolidinium iodide (P13I), which possesses a broad plastic phase from -36 to 135 degrees C, was doped with silica nanoparticles (SiO2 NPs) and 1-ethyl-3-methylimidazolium iodide (EMII), for the preparation of SiO2/EMII/P13I solid-state electrolytes for dye-sensitized solar cells (DSSCs). The thermal properties of all the electrolytes, including solid-solid phase transitions and melting temperatures, were investigated by differential scanning calorimetry (DSC). The effect of silica particles on the ionic conductivity, diffusion of I-/I-3(-) redox couple in electrolytes, and photovoltaic performance for solid-state DSSCs were investigated. The fabricated solid-state DSSCs yielded a high power conversion efficiency of 5.25% under simulated air mass 1.5 solar spectrum illuminations at 50 mW cm(-2). Furthermore, the DSSCs based on SiO2/EMII/P13I solid-state electrolytes show good stability after an accelerating aging test, demonstrating potential practical applications.
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