期刊
ACS APPLIED MATERIALS & INTERFACES
卷 4, 期 5, 页码 2757-2761出版社
AMER CHEMICAL SOC
DOI: 10.1021/am3003846
关键词
CuInSe2; Metal Chalcogenides; nanocrystals; photovoltaics; solar cells
资金
- Robert A. Welch Foundation [F-1464]
- Air Force Research Laboratory [FA-8650-07-2-5061]
- NSF Industry/University Cooperative Research Center on Next Generation Photovoltaics [IIP-1134849]
- Direct For Computer & Info Scie & Enginr
- Division Of Computer and Network Systems [1134849] Funding Source: National Science Foundation
Thin film photovoltaic devices (PVs) were fabricated with CuInSe2 (CIS) nanocrystals capped with either oleylamine, inorganic metal chalcogenide-hydrazinium complexes (MCC), or S2-, HS-, and OH-. A CIS nanocrystal layer deposited from solvent-based inks without high temperature processing served as the active light-absorbing material in the devices. The MCC ligand-capped CIS nanocrystal PVs exhibited power conversion efficiency under AM 1.5 illumination (1.7%) comparable to the oleylamine-capped CIS nanocrystals (1.6%), but with significantly thinner absorber layers. S2--capped CIS nanocrystals could be deposited from aqueous dispersions, but exhibited lower photovoltaic performance.
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