4.8 Article

Laser Engineered Multilayer Coating of Biphasic Calcium Phosphate/Titanium Nanocomposite on Metal Substrates

期刊

ACS APPLIED MATERIALS & INTERFACES
卷 3, 期 2, 页码 339-350

出版社

AMER CHEMICAL SOC
DOI: 10.1021/am100962m

关键词

laser coating; nanoparticles; BCP/Ti nanocomposite; functional gradient coating; interfacial bonding strength; biocompatibility

资金

  1. US National Science Foundation [CMMI 0802265]

向作者/读者索取更多资源

In this work, laser coating of biphasic calcium phosphate/titanium (BCP/Ti) nanocomposite on Ti-6Al-4V substrates was developed. A continuous wave neodymiumdoped yttrium aluminium garnet (ND:YAG) laser was used to form a robust multilayer of BCP/Ti nanocomposite starting from hydroxyapatite and titanium nanoparticles. In this process, low power coating is realized because of the strong laser-nanoparticle interaction and good, sinterability of nanosized titanium. To guide the optimization of laser processing conditions for the coating process, a multiphysics model Coupling electromagnetic module with heat transfer module was developed. This model was validated by laser coating experiments. Important features of the coated samples, including microstructures, chemical compositions, and interfacial bonding strength, were characterized. We found that a multilayer of BCP, consisting of 72% hydroxyapatite (HA) and 28% beta-tricalcium phosphate (beta-TCP), and titanium nanocomposite was formed on Ti-6Al-4 V substrates. Significantly, the coating/substrate interfacial bonding strength was found to be two times higher than that of the. commercial plasma sprayed coatings. Preliminary cell culture studies showed that the resultant BCP/Ti nanocomposite coating supported the adhesion and proliferation of osteoblast-like UMR-106 cells.

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