期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 1, 页码 36-40出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00692f
关键词
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资金
- National Natural Science Foundation of China [21402150, 21372267, 21572027]
- Chongqing University
An enantioselective [3 + 2] cycloaddition of heteroatom-substituted alkenes with alpha-substituted isocyanoacetates has been developed. The resulting cycloadducts could be further transformed to access a number of structurally diverse and biologically important pyrrolidine derivatives which bear sulfur-or oxygen-substituted quaternary stereocenters. Excellent reactivity and enantioselectivity were obtained for a broad range of substrates.
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