期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 8, 页码 1293-1296出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00016f
关键词
-
资金
- National Natural Science Foundation of China [21432006, 21625205]
A catalytic asymmetric ring-opening reaction of cyclopropyl ketones with beta-naphthols has been accomplished. In the presence of a chiral N,N'-dioxide/scandium(III) complex, a series of aromatic or vinyl substituted cyclopropyl ketones reacted with 2-naphthols, providing efficient access to chiral beta-naphthol derivatives in good yields (up to 99%) with good enantioselectivities (up to 97% ee). Notably, using the mixture of 2-naphthol substrates did not affect the efficiency of this catalytic system.
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