期刊
MATERIALS RESEARCH EXPRESS
卷 5, 期 1, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/aaa434
关键词
boron nitride nanosheet; sufactants; exfoliation; aqueous soluble
资金
- Radiation Technology R&D program through the NRF - Ministry of Science, ICT and Future Planning [NRF-2017M2A2A6A01019289]
- Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2015R1D1A3A01020192]
- International Joint Technology Development Project through the Ministry of Trade, Industry and Energy (MI, Korea) [N0002123]
- Korea Institute for KIAT
- Korea Evaluation Institute of Industrial Technology (KEIT) [N0002123] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [31Z20130012935, 2017M2A2A6A01019289, 2015R1D1A3A01020192] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Facile noncovalent surface functionalization of hydroxylated boron nitride nanosheet (BNNS-OH) was attempted through the sonication-assisted exfoliation of h-BN in aqueous media in the presence of bile acid-based surfactants such as sodium cholic acid (SC) or sodium deoxycholic acid (SDC), resulting in SC-or SDC-BNNS-OH dispersion with high up to 2mgml(-1) and enhanced dispersion stability due to the increased negative zeta potential. While prepared SC-BNNS-OH revealed multilayered BNNS structures, the large lateral sizes of hundreds nanometers and clear h-BN lattice structures are very promising for the preparation and application of water-processable BNNS-based nanomaterials. It is regarded that noncovalent functionalization of BNNS-OH based on sigma-pi interaction between with sigma-rich bile acid-based amphiphiles and pi-rich BNNS is very effective to formulate multi-functional BNNS-based nanomaterials or hybrids that can be utilized in various applications where both the pristine properties of BNNS and the extra functions are simultaneously required.
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