期刊
NANOMATERIALS
卷 8, 期 3, 页码 -出版社
MDPI
DOI: 10.3390/nano8030137
关键词
SWCNT; TFDO; epoxidation; nanocapsules filling
类别
资金
- PEOPLE Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme FP7 [290023]
- Regione Puglia MIUR PON Ricerca e Competitivita [20072013 Avviso 254/Ric. del 18/05/2011, PONa3 00369]
- University of Trieste
- Spanish Ministry of Economy and Competitiveness [SEV-2015-0496, SEV-2013-0295]
- CERCA programme
Methyl(trifluoromethyl) dioxirane (TFDO) can be used for the oxyfunctionalization of SWCNTs filled with Nal and LuCL3 under mild conditions. The chosen metal halides are of interest for theranostics, both for imaging and therapy when in their radioactive form. The applied functionalization methodology does not require metal catalyst, preserves the integrity of the nanotubes during treatment, avoiding the release of the filling material. In this way, epoxidation can be considered as an efficient methodology for the functionalization of carbon nanocapsules, where the traditional harsh oxidation conditions by acids are not applicable.
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