Article
Materials Science, Multidisciplinary
Joao P. Serra, Arkaitz Fidalgo-Marijuan, Joao C. Barbosa, Daniela M. Correia, Renato Goncalves, Jose M. Porro, Senentxu Lanceros-Mendez, Carlos M. Costa
Summary: This study focuses on the development of a hybrid solid polymer electrolyte (SPE) based on PVDF and MIL, and its battery cycling behavior at room temperature. The addition of MIL affects the morphology and properties of the MIL/PVDF blends. The ionic conductivity of the blends increases with temperature and MIL content.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Energy & Fuels
Wenxiang Chen, Zhihong Luo, Xiangqun Zhuge, Zhengping Ding, Yurong Ren, Adil Loya, Yibing Li, Kun Luo
Summary: In this study, an ionic liquid modified sulfonated poly(vinylidene fluoride) membrane was fabricated, which showed improved conductivity while maintaining impermeability and ionic selectivity. The application of this membrane in LOBs significantly extended cycle life and improved performance.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Green & Sustainable Science & Technology
Niranjanmurthi Lingappan, Lingxi Kong, Michael Pecht
Summary: This study evaluates the pros and cons of traditional PVDF binders, investigates the correlation between PVDF and capacity loss, and explores the research progress of aqueous-based binders. Despite the widespread interest in aqueous binders across various topics, their efficiency for largely expandable silicon anodes is unsatisfactory, highlighting the need for the development of high-performance binders for future battery technology.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2021)
Article
Chemistry, Multidisciplinary
Pan Zhang, Rui Li, Jian Huang, Boyu Liu, Mingjiong Zhou, Bizheng Wen, Yonggao Xia, Shigeto Okada
Summary: In this study, a flexible PVDF-HFP-based GPE doped with PEO and SiO2 was developed using a universal immersion precipitation method, which showed high ionic conductivity and lithium-ion transference number. The porous GPE enhanced the electrochemical performance of LiFePO4 cells, improving rate capability and cycling stability while inhibiting lithium dendrite growth for enhanced battery safety. The simplicity and potential of this novel GPE make it a promising candidate for high-performance Li-ion batteries.
Article
Chemistry, Multidisciplinary
S. Vauthier, M. Alvarez-Tirado, G. Guzman-Gonzalez, L. C. Tome, S. Cotte, L. Castro, A. Gueguen, D. Mecerreyes, N. Casado
Summary: The role of binders is crucial to achieve high performance and long cycle lives in next-generation electrodes for lithium batteries. In this study, PDADMA poly(ionic liquid)s with fluorinated anions were used as cathode binders in Li-ion and Li-air batteries, showing improved cell performances and enhanced capacity values, rate performance, and cycling stability. The proposed fluorinated PDADMA Poly(ionic liquid)s can be a highly competitive alternative to conventional binders used nowadays in Li-ion and Li-air batteries.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Chemistry, Physical
Joao C. Barbosa, Rafael S. Pinto, Loic Hilliou, Maria. M. Silva, Carlos M. Costa, Renato Goncalves, Senentxu Lanceros-Mendez
Summary: The study utilized P(VDF-TrFE-CFE) terpolymer as a new polymer binder to successfully prepare high-performance printable lithium-ion battery cathodes, demonstrating better performance compared to electrodes prepared with traditional P(VDF) binder.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Materials Science, Characterization & Testing
Insun Woo, Jong In Lee, Dong Je Han, Dong-Heon Han, Seung-Ju Oh, Jae Uk Yoon, Soon-Mok Choi, Eun-Ho Sohn, Jin Woo Bae
Summary: To solve the problem of bacterial growth on PVDF surfaces, pyridinium group grafted-PVDF (Pyd-PVDF) was added to PVDF to prepare antibacterial materials. The antibacterial PVDF-based blends were prepared by melt-blending of PVDF and Pyd-PVDF, and their structural, thermal, mechanical, and antibacterial properties were characterized. The impact strengths and elongations of the blends increased with increasing Pyd-PVDF concentration, while the flexural moduli and tensile strengths slightly decreased.
Review
Chemistry, Multidisciplinary
Shengyu Zhou, Shijie Zhong, Yunfa Dong, Zhezhi Liu, Liwei Dong, Botao Yuan, Haodong Xie, Yuanpeng Liu, Liang Qiao, Jiecai Han, Weidong He
Summary: Poly(vinylidene fluoride) (PVDF) solid polymer electrolytes (SPEs) with excellent flexibility, mechanical property, and high electrochemical and thermal stability have huge potential in solid-state lithium batteries. However, PVDF SPEs suffer from low ionic conductivity, high crystallinity, and low reactive sites. The development of PVDF-based composite solid polymer electrolytes (CSPEs) is an effective strategy to optimize the electrolyte performance. This review introduces the recent progress of PVDF-based SPEs, focusing on the enhancement of ionic conductivity and interface regulation through modified fillers. The applications of PVDF-based SPEs in Li-S and Li-O-2 battery systems are also discussed.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Jorge L. Olmedo-Martinez, Luca Porcarelli, Gregorio Guzman-Gonzalez, Itxaso Calafel, Maria Forsyth, David Mecerreyes, Alejandro J. Muller
Summary: This article investigates the blending strategy of PEO with PLA in solid-state lithium batteries to extend their use at high temperatures (100 degrees C). The addition of PLA enhances the mechanical properties of the electrolytes and leads to higher ionic conductivities at elevated temperatures.
ACS APPLIED POLYMER MATERIALS
(2021)
Article
Chemistry, Physical
Kaibo Fan, Xianxin Lai, Zhiqi Zhang, Lili Chai, Qingchao Yang, Guanghao He, Song Liu, Ling Sun, Yong Zhao, Zhengguang Hu, Li Wang
Summary: In this study, dual-salt modification of PVDF-based polymer electrolytes was proposed to enhance lithium ion transport channels, leading to improved ionic conductivity and good application prospects in solid-state lithium metal batteries.
JOURNAL OF POWER SOURCES
(2023)
Article
Polymer Science
Nicolas Maria, Jon Maiz, Daniel E. Martinez-Tong, Angel Alegria, Fatimah Algarni, George Zapzas, Nikos Hadjichristidis, Alejandro J. Mueller
Summary: By comparing the crystallization and morphology of two linear diblock copolymers and blends, it was found that the diblock copolymers are miscible in the melt state while the blends are immiscible. The crystallization of PVDF is strongly influenced by its environment, with different polymorphic compositions induced by cooling rate or crystallization temperature.
Article
Electrochemistry
Ge Yuan, Haijun Guo, Li Bo, Mengkun Wang, Hairong Zhang, Xinde Chen
Summary: The composite membrane PDFP-POPM, prepared by blending PDFP and POPM, exhibited a porous structure and high ionic conductivity. The lithium ion transference number of the gel polymer electrolyte (GPE) based on PDFP-POPM was higher than that of other GPEs. The battery using PDFP-POPM as electrolyte showed good electrochemical stability and cycling performance.
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2023)
Article
Chemistry, Physical
Hongmei Liu, Qingping Wu, Xiang Guan, Mian Liu, Fei Wang, Ruijiang Li, Jun Xu
Summary: Researchers have designed and synthesized a self-healing polymer binder (PAA-TUEG) that improves the electrochemical performance and cycle life of silicon anode materials. This binder combines high Li-ion conductivity and self-healing ability, offering a new approach for next-generation batteries using high-capacity materials.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Qingchuan Du, Shumin Shi, Lida Zhang, Zhongyuan Yan, Xu Zeng, Jingjing Wu, Weixin Zhou, Zhen-Dong Huang, Titus Masese, Yanwen Ma
Summary: The study developed separators based on the building concept of a bird's nest, consisting of SiO2 nanowires reinforced with PVDF-HFP. Compared to bare SiO2 nanowire separators, the hybrid separators show improved mechanical properties due to a strong crosslink effect, while maintaining excellent electrolyte wettability and ionic conductivity. Lithium metal batteries with these hybrid separators exhibit excellent rate performance and cyclic stability.
Article
Chemistry, Physical
Yi-Pei Chuang, Yi-Long Lin, Chih-Chieh Wang, Jin-Long Hong
Summary: The dual cross-linked network cxPAA-PEI(x) composed of PAA and PEI is an efficient binder for silicon anodes in lithium-ion batteries, providing both physical hydrogen bonds and chemical covalent bonds. By adjusting the PEI content, the mechanical properties and adhesive forces of the binders can be tailored, with cxPAA-PEI(3) showing the best performance.
ACS APPLIED ENERGY MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Yu Wang, Xuewei Fu, Min Zheng, Wei-Hong Zhong, Guozhong Cao
ADVANCED MATERIALS
(2019)
Review
Materials Science, Multidisciplinary
Yichao Li, Xianrong Huang, Lijian Zeng, Renfu Li, Huafeng Tian, Xuewei Fu, Yu Wang, Wei-Hong Zhong
JOURNAL OF MATERIALS SCIENCE
(2019)
Article
Chemistry, Multidisciplinary
Chunhui y Li, Xuewei Fu, Weihong Zhong, Jin Liu
Article
Chemistry, Multidisciplinary
Chenfeng Ding, Xuewei Fu, Hao Li, Jiayi Yang, Jin-Le Lan, Yunhua Yu, Wei-Hong Zhong, Xiaoping Yang
ADVANCED FUNCTIONAL MATERIALS
(2019)
Article
Electrochemistry
Lushi Kong, Xuewei Fu, Shengli Qi, Dezhen Wu, Yu Wang, Wei-Hong Zhong
ELECTROCHIMICA ACTA
(2019)
Review
Chemistry, Physical
Xuewei Fu, Wei-Hong Zhong
ADVANCED ENERGY MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Min Chen, Xuewei Fu, Noah David Taylor, Zhiping Chen, Wei-Hong Zhong
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2019)
Article
Engineering, Chemical
Juejing Liu, Francis O. Dunne, Xin Fan, Xuewei Fu, Wei-Hong Zhong
SEPARATION AND PURIFICATION TECHNOLOGY
(2019)
Article
Chemistry, Physical
Min Chen, Chunhui Li, Xuewei Fu, Wei Wei, Xin Fan, Andrew Hattori, Zhiping Chen, Jin Liu, Wei-Hong Zhong
ADVANCED ENERGY MATERIALS
(2020)
Article
Chemistry, Physical
Chenfeng Ding, Lingbo Huang, Yiran Guo, Jin-le Lan, Yunhua Yu, Xuewei Fu, Wei-Hong Zhong, Xiaoping Yang
ENERGY STORAGE MATERIALS
(2020)
Article
Chemistry, Physical
Chunhua Ying, Xuewei Fu, Wei-Hong Zhong, Jin Liu
Summary: Through DFT calculations in a vacuum space, the ion interaction and transport mechanisms in protein solid electrolytes were investigated, revealing that charged amino acids can lock anions and facilitate ion transport. Soy protein electrolyte with abundant charged amino acids exhibited higher ionic conductivity and lower activation energy compared to zein electrolyte lacking charged amino acids.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Materials Science, Multidisciplinary
Dan Li, Zhiwei Zhu, Ziyu Zhao, Yuan Ji, Xuewei Fu, Zunfeng Liu, Wei Yang, Yu Wang
Summary: Helix-fiber composites (HFCs) are used in intelligent stretchable materials or devices by wrapping a flexible core. The mechanical coupling between the core and wrapping plays a critical role in controlling the structure and mechanical properties of HFCs. The results show that the mechanical properties of HFCs can be programmed by adjusting the mechanical coupling strength, and they also exhibit unique pseudo-elastic behavior. Additionally, HFCs can function as an elastic conductor, sensor, and elastic mold for structure transplantation by decoupling the elastomer core from the helix fiber.
COMMUNICATIONS MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xuewei Fu, Francis Dunne, Min Chen, Wei-Hong Zhong
Article
Chemistry, Physical
Xuewei Fu, Louis Scudiero, Wei-Hong Zhong
JOURNAL OF MATERIALS CHEMISTRY A
(2019)
Article
Chemistry, Physical
Yichao Li, Xuewei Fu, Yu Wang, Wei-Hong Zhong, Renfu Li
ENERGY STORAGE MATERIALS
(2019)