期刊
NANO ENERGY
卷 48, 期 -, 页码 238-247出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2018.03.053
关键词
Lithium-ion batteries; CoFe2O4 nanosheets; N-doped carbon fibers; Binder-free anode
类别
资金
- National Natural Science Foundation of China [51672055]
- Fundamental Research Funds for the Central Universities [HEUCF201709]
- Natural Science Foundation of Heilongjiang Province [LC2016017]
- Ten Thousand Talent Program [W02020249]
There are crucial demands for high power density and long-term cycling performance of Li-ion batteries (LIBs), and the development of stable electrode material operating at high current densities still remains a challenge. Here we develop a novel strategy for the synthesis of flexible N-doped carbon nanofiber/CoFe2O4 film (CoFe2O4@N-CNF) with a double-layer carbon protection by electrospinning, which possesses (s)table carbon shell and honeycomb-like core with CoFe2O4 nanosheets embedded into conductive and interconnected carbon nanosheets. The unique structure is beneficial for providing robust structural stability upon long-term cycling, and offering nitrogen-rich interconnected mesoporous and conductive carbon matrix for fast charge and ion transport. As a consequence, the optimized CoFe2O4@N-CNF exhibits a high reversible capacity of 858 mAh g(-1) at 0.1 A g(-1), excellent rate capability (306 mAh g(-1) at 30 A g(-1)), and superior cycling stability up to 10,000 cycles with almost no capacity loss at 10 A g(-1). We believe that this proposed methodology has a profound impact on drastic improvements of various flexible energy storage devices.
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