Article
Polymer Science
Xiu-Ting Li, Xiao-Meng Zhu, Jie Dong, Xin Zhao, Qing-Hua Zhang
Summary: The addition of HBPSi significantly reduced the dielectric constants of the PI/HBPSi composite resins without compromising their processability and thermal stability. Furthermore, the PI resin containing 10% HBPSi exhibited better fiber bonding ability with higher interfacial shear strength and adhesion strength compared to the neat PI-6 matrix. These composite resins show great potential as low-dielectric constant resin matrix in radar radome.
CHINESE JOURNAL OF POLYMER SCIENCE
(2021)
Article
Chemistry, Applied
Kaiming Yang, Junshan Yuan, Yuanbo Zhang, Rui Liu, Weixu Feng, Gaofeng Shang, Hongxia Yan
Summary: A high-performance polyimide bonded solid lubricating coating with excellent adhesion, friction properties, wear life, and load carrying capacity was successfully prepared. This study provides an important direction for the design and preparation of high-performance bonded solid lubricating coatings.
PROGRESS IN ORGANIC COATINGS
(2022)
Article
Materials Science, Multidisciplinary
Zhengxiang Zhou, Gebin Shen, Xinrong Huang, Chuanhui Yang, Yingfeng Yu
Summary: In this study, a series of polyimides and polyimide-b-polysiloxane copolymers were fabricated to minimize the internal stress between the polymer and substrates. The results showed that the internal stress decreased significantly with the copolymerization of polyimides and polysiloxanes, and the copolymer had a similar coefficient of thermal expansion to copper.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Polymer Science
Gang Lv, Songpei Xie, Danbo Mao, Ge Ren, Shibin Wu, Wei Yang
Summary: An optically homogeneous polyimide film with desirable atomic oxygen erosion durability was fabricated by copolycondensation of amine-functionalized hyperbranched polysiloxane and pristine polyimide. The resulting hybrid showed significantly reduced mass loss and stable thickness uniformity under atomic oxygen attack, making it suitable for ultra-lightweight space optical elements in low earth orbit. Additionally, the hybrid film exhibited satisfactory mechanical properties, including a tensile strength of 228.9 MPa and elongation at break of 7.3%.
HIGH PERFORMANCE POLYMERS
(2021)
Article
Engineering, Environmental
Lisha Zhai, Zhiyu Huang, Yuxin Luo, Huiyu Yang, Tonghe Xing, Annan He, Zhenwei Yu, Jie Liu, Xiaofang Zhang, Weilin Xu, Fengxiang Chen
Summary: Researchers have successfully chemically bonded a uniform and thickness-controlled amorphous TiO2 coating onto the surface of aramid fiber using a modified atomic layer deposition (mALD) technique, resulting in high anti-UV efficiency while preserving the mechanical characteristics and flexibility of the fiber. The modified aramid fibers exhibit significant retention of initial strength even after prolonged exposure to high-intensity UV irradiation, demonstrating their potential for future innovative applications in multifunctional fibers and devices.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Polymer Science
Liuyue Zhong, Tingcheng Li, Junheng Zhang, Junsheng Wang, Daohong Zhang
Summary: In this study, hyperbranched phosphorus-containing polysiloxane functionalized halloysite nanotubes were synthesized for the preparation of epoxy composites with improved mechanical strength and flame retardancy, without sacrificing the glass transition temperature.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Materials Science, Multidisciplinary
Sensen Zheng, Jie Dong, Xinyan Zhou, Xiuting Li, Xin Zhao, Qinghua Zhang
Summary: In this study, high-strength and high-modulus polyimide fibers were synthesized by adjusting the ratio of raw materials and the hot-drawing process. The relationship between the mechanical properties and aggregation structure of the fibers was investigated, and the fibers exhibited excellent UV irradiation and ozone aging resistance, as well as prominent thermal stability.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Fengxiang Chen, Lisha Zhai, Huiyu Yang, Shichao Zhao, Zonglei Wang, Chong Gao, Jingyi Zhou, Xin Liu, Zhenwei Yu, Yong Qin, Weilin Xu
Summary: The study successfully enhanced the UV resistance and laundering durability of aramid fibers through a dual-layer ultrathin Al2O3-TiO2 coating. During testing with high temperature and intense UV light exposure, the fibers only experienced a decrease in tenacity of approximately 0.85%.
Article
Polymer Science
Lihua Bai, Hongxia Yan, Liulong Guo, Miaomiao He, Tian Bai, Pengfei Yang
Summary: By grafting renewable oleic acid onto water-soluble HBPSi, a compact supramolecular structure was constructed, leading to enhanced fluorescence and drug loading capacity, with drug release controlled by pH. The supramolecular structure is sensitive to Fe3+ and can be applied in drug delivery and Fe3+ sensing.
MACROMOLECULAR CHEMISTRY AND PHYSICS
(2021)
Article
Chemistry, Multidisciplinary
Shunxi Song, Yujie Shi, Jiaojun Tan, Zeshi Wu, Meiyun Zhang, Sheng Qiang, Jingyi Nie, Haitang Liu
Summary: Polyimide sponges with a unique three-dimensional structure and outstanding performance have bright prospects in weight reduction, heat insulation, and sound absorption equipment in aerospace, navigation, and other areas. This study proposes an efficient and scalable water-based foam forming approach to fabricate ultralight and porous polyimide/aramid sponges (PASG). The PASGs, with high porosity, ultra-low density, and excellent thermal and sound insulation performance, offer more possibilities for developing high-performance thermal insulation and noise reduction materials.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2022)
Article
Materials Science, Characterization & Testing
Qing Li, Yujuan Guo, Chaoliu Ouyang, Shunmin Yi, Sheng Liu
Summary: Polydopamine (PDA), also known as artificial melanin, was used to prepare a series of porous highly fluorinated polyimide/polydopamine (FPI/PDA) films via cyclodehydration. The films showed reinforced thermal, mechanical, UV-shielding, and photostability properties due to the hydrogen bond and porous structure. The addition of PDA improved the tensile strength and fracture elongation, reaching a maximum at 0.5 wt % PDA content. The porous FPI/PDA film exhibited excellent UV-shielding properties and visible light transmittance, as well as durability after UV irradiation.
Article
Materials Science, Multidisciplinary
Lijie Yu, Qiangsheng Hu, Tingcheng Li, Junheng Zhang, Shenghui Chen, Zejun Xu, Sufang Chen, Daohong Zhang
Summary: Lightweighting of automotives is crucial for reducing fuel and energy consumption, CO2 emission, and environmental pollution. Polymer composites, particularly high-strength glass fiber/polyamide (GF/PA) composites, have potential in lightweighting, but their performance is insufficient. In this study, a stearate-ended hyperbranched polyester (HBP-12-n) is designed to prepare high-performance GF/PA6 composites with high GF content. The flowability of the composites can be further increased by combining carboxyl-ended hyperbranched polymer (HyPer C181) with HBP-12-n. The simultaneous improvement in melt flow index (MFI) and impact strength of GF/PA6 composites, along with the proposed synergistic mechanism, opens up prospects for lightweight automotive parts and reduction of CO2 emissions.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2023)
Article
Engineering, Manufacturing
Wenjie Huang, Jingshu Huang, Bin Yu, Yuan Meng, Xianwu Cao, Qunchao Zhang, Wei Wu, Dean Shi, Tao Jiang, Robert K. Y. Li
Summary: A novel phosphorus-containing hyperbranched polysiloxane (P-HBPSi) was synthesized and utilized to functionalize graphene oxide, showing outstanding flame retardancy and toxic gas suppression properties when incorporated into TPU nanocomposites.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2021)
Article
Chemistry, Physical
Lin Tang, Xiaoli Fan, Yusheng Tang, Junliang Zhang, Jie Kong, Junwei Gu
Summary: The surface activity and UV resistance of PBO fibers were enhanced by fabricating the Ce0.8Ca0.2O1.8/P(S-co-BCB-co-MMA) organic-inorganic hybrid coating, leading to improved interfacial bonding strength with modified BADCy resins.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Applied
Feng Gao, Xianrui Zhang, Ling Weng, Yujun Cheng, Jiahao Shi
Summary: This study investigated the modification of phenolic epoxy vinyl ester resin (PEVER) with hyperbranched polyimide (HBPI) and its impact on the resin properties. The results showed that the addition of HBPI enhanced the toughness and thermal stability of PEVER, while decreasing the dielectric constant and dielectric loss.
PIGMENT & RESIN TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Mengjiao Dong, Liyun Liao, Chensheng Li, Yingxiao Mu, Yanping Huo, Zhong-Min Su, Fushun Liang
Summary: This study investigates the influence of the polarity of polymer matrices on persistent room-temperature phosphorescence (pRTP). It is discovered that intense phosphorescence emission can be achieved in highly polar matrices such as polyacrylic acid (PAA). The dipole-dipole interaction between the polar fluorophore and polar matrix is proposed to stabilize the excited state and facilitate the generation of efficient room-temperature phosphorescence emissions.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Han-Jiang Yang, Weijia Xiang, Xiangzhou Zhang, Jin-Yun Wang, Liang-Jin Xu, Zhong-Ning Chen
Summary: This article reports a 2D copper(I)-based cluster material for X-ray imaging, which exhibits ultra-high spatial resolution, high photoluminescence efficiency, and low detection limit. The material shows excellent linear response to X-ray dose rates and light output, and has the best spatial resolution among reported lead-free metal halide hybrids.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Review
Materials Science, Multidisciplinary
Taek Joon Kim, Sang-hun Lee, Dayeong Kwon, Jinsoo Joo
Summary: Donor-acceptor heterostructures using organic-inorganic halide perovskites, two-dimensional transition metal dichalcogenides, pi-conjugated organic small/macro molecules, and quantum dots are promising platforms for exciton-based photonics and optoelectronics. Hetero-interlayer excitons and hetero-intermolecular excitons formed through optical and/or electrical charge transfer in various heterostructures are important quasi-particles for light emission, detection, and harvesting systems.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Liemao Cao, Xiaohui Deng, Zhen-kun Tang, Rui Tan, Yee Sin Ang
Summary: We investigate the interface properties between WSi2N4 and Mo2B, O-modified Mo2B, and OH-modified Mo2B nanosheets. We find that WSi2N4 and Mo2B form n-type Schottky contacts, while functionalizing Mo2B with O and OH leads to the formation of both n-type and p-type ohmic contacts with WSi2N4. Additionally, we demonstrate the emergence of quasi-ohmic contact with ultralow lateral Schottky barrier and zero vertical interfacial tunneling barriers in Mo2B(OH)2-contacted WSi2N4.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Ga Eun Kim, Hae-Jin Kim, Heesuk Jung, Minwoo Park
Summary: This study presents a solution to the commercialization challenges of flexible LEDs based on MAPbBr(3) by incorporating polyurethane and an In-Ga-Zn-Sn liquid alloy. The designed devices showed high flexibility, efficiency, and durability, with improved electron injection and reduced defects, making them promising for next-generation displays.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Tao Shen, Zeng Wu, Zhen Jiang, Dongsheng Yan, Yan Zhao, Yang Wang, Yunqi Liu
Summary: Sidechain engineering is an important molecular design strategy for tuning the solid-state packing and structural ordering of conjugated polymers. The effects of sidechain direction on the optoelectronic properties of polymers and device performance were systematically investigated in this study. The results demonstrate that tuning the sidechain substitution direction can effectively improve the molecular structure and light absorption properties of polymers, providing new insights for the rational design of functional polymers.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Lotte Clinckemalie, Bapi Pradhan, Roel Vanden Brande, Heng Zhang, Jonathan Vandenwijngaerden, Rafikul Ali Saha, Giacomo Romolini, Li Sun, Dirk Vandenbroucke, Mischa Bonn, Hai I. Wang, Elke Debroye
Summary: In this study, a facile strategy using a non-conductive polymer was proposed to fabricate stable, pinhole-free thick films. The effect of introducing a second phase into CsPbBr3 perovskite crystals on their photophysical properties and charge transport was investigated. The dual phase devices exhibited improved stability and more effective operation at higher voltages in X-ray detection.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Jingye Zou, Shenglan Hao, Pascale Gemeiner, Nicolas Guiblin, Omar Ibder, Brahim Dkhil, Charles Paillard
Summary: When rare-earth ions are embedded in a ferroelectric material, their photoluminescence can serve as an all-optical probe for temperature, electric field, and mechanical stimulus. However, the impact of ferroelectric phase transitions on photoluminescence is not well understood. In this study, we demonstrate changes in the photoluminescence of green emission bands during critical ferroelectric transitions in an Er-doped BaTiO3 material. We also find that the intensity ratio and wavelength position difference of sub-peaks provide information on the phase transitions.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Jiangchao Han, Daming Zhou, Wei Yang, Chen Lv, Xinhe Wang, Guodong Wei, Weisheng Zhao, Xiaoyang Lin, Shengbo Sang
Summary: Rare type-II spin-gapless semiconductors (SGSs) have attracted increasing attention due to their unique spin properties. In this study, the interface contacts and spin transport properties of different devices composed of VSi2P4 ferromagnetic layers were investigated. The results show that VSi2P4 is a promising material for designing vertical van der Waals heterostructures with a giant tunnel magnetoresistance (TMR) in spintronic applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Tianqi Zhao, Renagul Abdurahman, Qianting Yang, Ruxiangul Aiwaili, Xue-Bo Yin
Summary: In this study, we designed and prepared Cr and Ba-doped gamma-Ga2O3 nanoparticles to achieve near-infrared emission and enhance the emission intensity. The emission mechanism was proposed based on the trap depth, band gap, and energy levels of Cr ions. The ratiometric temperature sensing and encryption information transfer demonstrated the potential applications of this technology.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Shuvankar Gupta, Jyotirmoy Sau, Manoranjan Kumar, Chandan Mazumdar
Summary: In this study, a new spin-gapless semiconductor material CoFeMnSn is reported, and its stable structure and spin-polarized band structure are determined through experimental realization and theoretical calculations. The compound exhibits a high ferromagnetic transition temperature, making it excellent for room temperature applications. The nearly temperature-independent resistivity, conductivity, and carrier concentration of the compound, adherence to the Slater-Pauling rule, and the high intrinsic anomalous Hall conductivity achieved through hole doping further confirm its spin-gapless semiconductor nature. Additionally, the compound's SGS and topological properties make it suitable for spintronics and magneto-electronics devices.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Ikumi Aratani, Yoji Horii, Yoshinori Kotani, Hitoshi Osawa, Hajime Tanida, Toshiaki Ina, Takeshi Watanabe, Yohko F. Yano, Akane Mizoguchi, Daisuke Takajo, Takashi Kajiwara
Summary: In this study, two-dimensional arrays of single-molecule magnets (SMMs) based on metal-organic frameworks (MOFs) were systematically modified through Langmuir-Blodgett methods and chemical modifications. The introduction of bulky alkoxide groups induced structural changes and perpendicular magnetic anisotropy. This research provides a promising strategy for the construction of high-density magnetic memory devices using molecular spintronics.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Zonghao Lei, Houhe Dong, Lijie Sun, Bing Teng, Yanfei Zou, Degao Zhong
Summary: Researchers have successfully developed four different up-conversion phosphors based on the Eulytite-type host Ba3Yb(PO4)(3). The optical temperature sensing properties of these phosphors were thoroughly investigated, and it was found that Ba3Yb(PO4)(3):Tm/Er/Ho showed potential for optical temperature measurement applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
C. Roncero-Barrero, M. A. Carvajal, J. Ribas-Arino, I. de P. R. Moreira, M. Deumal
Summary: This study computationally investigates the conductivity of four isostructural compounds with different Se contents, and reveals the parameters that define their conductivity in stable organic radical materials. The results provide insights into the influence of Se content on the conductivity and highlight the importance of considering multiple parameters in understanding the trends in conductivity.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)
Article
Materials Science, Multidisciplinary
Remi Arras, Kedar Sharma, Lionel Calmels
Summary: In this study, we investigated the interplay between structural defects in NiFe2O4, showing that the complex formed by a Ni-Oh/Fe-Td-cation swap and a neutral oxygen vacancy is more stable than these two isolated defects, and significantly reduces the width of the minority-spin band gap.
JOURNAL OF MATERIALS CHEMISTRY C
(2024)