4.6 Article

Imprinted MoS2 achieve highly efficient self-separative molecule extraction

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 6, 期 17, 页码 7395-7400

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta01854e

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资金

  1. National Natural Science Foundation of China [21673243]
  2. Guangdong-Hong Kong Joint Innovation Project of Guangdong Province, China [2014B050505015]
  3. Special Support Program of Guangdong Province, China [2014TQ01N610]
  4. Project of Science and Technology Service Network initiative, Chinese Academy of Sciences [KFJ-STS-QYZD-010]
  5. Tibet Autonomous Region Major Special Projects [ZD20170017]

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Imprinting is a biological process where a young animal acquires several of its behavioural characteristics from its parent and then follows themaround and is called filial imprinting. However, imprinting can implicitly be inside the materials that possess a suitable affinity to integrate themselves with the surrounding liquid environment. In this research, an example of imprinting in molybdenum disulfide (MoS2) nanosheets was demonstrated. The as-prepared MoS2 containing a polar edge and low-polar plane faces on its flower-like morphology give it an imprinting ability to adhere to water or n-hexane. Therefore, imprinted MoS2 tends to retain the phase of the imprinting solvent, which is called solvent identification. More interestingly, imprinted MoS2 can in addition fulfill a highly efficient heterophasic extraction of rhodamine B (RhB) from water to n-hexane or lauric acid from n-hexane to water in seconds. At the same time, imprinted MoS2 solvent identification exhibits rapid self-separation after shaking, which avoids tedious centrifugation and filtration in a separation-purification process and makes it more convenient.

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