Article
Engineering, Environmental
Cunyun Xu, Yanqing Yao, Gang Wang, Jun Dong, Gaobo Xu, Yuanxing Zhong, Dengcheng Lu, Xusheng Zhao, Debei Liu, Guangdong Zhou, Xiude Yang, Ping Li, Lijia Chen, Qunliang Song
Summary: PEDOT:PSS is commonly used in inverted perovskite solar cells for its simple preparation process, high stability, and light transmittance. A self-woven deposition method has been proposed to prepare a pinhole-free monolayer PEDOT:PSS mesh, which significantly boosts the power conversion efficiency of the device. The high performance is attributed to improved light absorption and energy-level alignment, as well as enhanced hole extraction efficiency.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Meichen Guo, Wu Tang, Chenbin Tang, Xuesong He, Jiahui Hu, Cong Fan
Summary: A strategy called surface self-carbonization is developed to solve the dissolution issue of small-molecule organic cathodes in potassium-ion batteries. By controlling the carbonization temperature and time, a carbon protective layer can be formed on the surface of NTCDI-DAQ particles, significantly increasing their insolubility and improving cathode performance in PIBs.
Article
Chemistry, Physical
Mingchuang Chen, Zhongjue Wu, Jinlei Wu, Jie Tang, Zhiyuan Yang, Xu Zheng, Zexin Chen, Wanzhu Cai, Feipeng Zheng, Jifu Shi
Summary: In this study, a convenient and cost-effective method for fabricating a bio-inspired hybrid super-wettable surface (HSWS) using imprinted MoS2 was presented. By imprinting MoS2 nanoflowers with amino acid and octadecane, hydrophilic and hydrophobic properties were endowed. The water collection efficiency factor (eta) of the HSWS based on heterogeneous MoS2 compositions and blending ratio outperformed that of the homogeneous MoS2. The optimal proportion (6:4) of hydrophobic and hydrophilic MoS2 achieved an eta of 20%, which was double that of the pure MoS2 sample, demonstrating the synergy effect during fog harvesting.
APPLIED SURFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Shujie Xiao, Ling Huang, Wei Lv, Yan-Bing He
Summary: A hybrid interlayer composed of Ti-2(SO4)(3)/carbon composite layer-coated Li1.3Al0.3Ti1.7(PO4)(3) (CLATP) and graphene was developed to effectively block the diffusion of polysulfide anions while allowing rapid Li ion transfer, significantly inhibiting self-discharge and boosting cyclic stability of Li-S batteries. This innovative design exhibited high discharge capacity with extremely low capacity fading and no self-discharge even after resting for extended periods.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Environmental
Hao Li, Luyan Li, Jun Wen, Gang Ye, Jing Chen, Xiaolin Wang
Summary: The phosphorylcholine (PC) functionalized polymeric adsorbent PAN-PC exhibits an unprecedented self-assembly effect in the adsorption of uranyl, resulting in an ultrahigh stoichiometric ratio (>5:1) and remarkable adsorption capacity (2658 mg g(-1)). Furthermore, PAN-PC demonstrates practicality in seawater and simulated nuclear wastewater. This work introduces a novel strategy of utilizing self-assembly effect to significantly enhance adsorption performance and provides a new approach for the development of efficient adsorbents for metal ions.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Multidisciplinary Sciences
Zhenyu Shi, Xiao Zhang, Xiaoqian Lin, Guigao Liu, Chongyi Ling, Shibo Xi, Bo Chen, Yiyao Ge, Chaoliang Tan, Zhuangchai Lai, Zhiqi Huang, Xinyang Ruan, Li Zhai, Lujiang Li, Zijian Li, Xixi Wang, Gwang-Hyeon Nam, Jiawei Liu, Qiyuan He, Zhiqiang Guan, Jinlan Wang, Chun-Sing Lee, Anthony R. J. Kucernak, Hua Zhang
Summary: Crystal phase is a crucial factor that determines the properties and functions of two-dimensional transition-metal dichalcogenides (TMDs). In this study, MoS2 nanosheets with high phase purity were synthesized, and it was found that the 2H-phase template facilitated the epitaxial growth of Pt nanoparticles, while the 1T' phase supported single-atomically dispersed Pt atoms. This research provides valuable insights into the relationship between crystal phase and catalyst development.
Article
Chemistry, Analytical
Ningge Jian, Yuanyuan Dai, Li-E Liu, Di Wu, Yongjun Wu
Summary: Utilizing PAN NFsM as a template, MIR/PDA NFsM was synthesized to extract SAs in water, showing significantly improved adsorption performance and mass transfer efficiency. A new SPE method based on MIR/PDA NFsM was successfully developed for detecting SAs in environmental water, with remarkable enrichment factors, low detection limits, broad linear range, and satisfactory recoveries and precisions. The reusability and storage stability of MIR/PDA NFsM make it highly valuable for practical applications.
Article
Chemistry, Analytical
Xiaoyu Xie, Jing Li, Xueyan Zhen, Liang Chen, Wanqing Yuan, Quan Feng, Xia Liu
Summary: In this study, a novel fluorescent molecular imprinted nanoplatform was constructed for efficient recognition and determination of glycoproteins. The platform showed high adsorption capacity and rapid binding kinetics, with satisfying selectivity and sensitivity. Its efficiency and applicability were validated by detecting ovalbumin in egg white samples.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Inorganic & Nuclear
Zhaoyang An, Hui Xue, Jing Sun, Niankun Guo, Tianshan Song, Jiawen Sun, Yi-Ru Hao, Qin Wang
Summary: Integrating anion vacancies and heterostructures into catalytic materials improves electron and ion transport, enhances structural stability, and promotes overall water splitting activity.
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Linda Feuerstein, Carl Georg Biermann, Zuyao Xiao, Christian Holm, Juliane Simmchen
Summary: The study expands the range of suitable reactions for micromotors by exploring galvanic exchange processes, resulting in a highly efficient new type of active motility. An electrokinetic model is proposed to better understand the underlying processes involved in micromotor propulsion.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Analytical
Jianxing Xiang, Peipei Zhou, He Mei, Xiaodong Liu, Huili Wang, Xuedong Wang, Yanyan Li
Summary: Highly efficient hydrophobic molecularly imprinted magnetic covalent organic frameworks (MI-MCOF) nanocomposites were synthesized using a facile Schiff-base reaction. The MI-MCOF exhibited superior magnetic responsivity and affinity, as well as high selectivity and kinetics for bisphenol A (BPA) in water and urine samples. The combination of MI-MCOF-MSPE with HPLC-FLD provided excellent analytical performance for selective extraction of BPA from complex matrices, replacing traditional magnetic separation and adsorption materials.
Article
Biotechnology & Applied Microbiology
Asmaa S. Morshedy, Hager R. Ali, Amr A. Nada, Abdelrahman M. Rabie, Heba H. El-Maghrabi
Summary: The study utilized a well-prepared imprinted nanocomposite polymer as a highly photo-active material for oxidative desulfurization process, achieving a high efficiency of dibenzothiophene degradation. By adjusting experimental parameters such as radiation source, catalyst dosage, reaction time, and addition of oxidizing agents, sulfur compounds can be rapidly removed at room temperature. The material exhibited not only efficient desulfurization under optimal conditions, but also excellent recyclability for multiple uses.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2021)
Article
Chemistry, Physical
Heba A. Kashmery, Soliman I. El-Hout
Summary: New strategies are needed to completely remove various contaminants from water. Researchers developed MoS2/CeO2 heterojunctions as photocatalysts to degrade Atrazine. The optimized photocatalyst exhibited efficient removal of Atrazine under visible light and demonstrated excellent recyclability.
SURFACES AND INTERFACES
(2023)
Article
Biochemistry & Molecular Biology
Zhimin Liu, Qingqing Zhou, Dan Wang, Yunli Duan, Xuehua Zhang, Yi Yang, Zhigang Xu
Summary: The novel high-throughput array analytical platform based on derived beta-cyclodextrin supramolecular imprinted polymer (SMIP) fibers shows great potential in selective enrichment and removal of parabens, leading to a specific and sensitive recognition method for parabens analysis in environmental water when combined with HPLC.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Physical
Teng Guo, Yuan Lei, Xin Hu, Guang Yang, Jie Liang, Qiang Huang, Xiancai Li, Meiying Liu, Xiaoyong Zhang, Yen Wei
Summary: This study reported a simple hydrothermal method for preparing Ti3C2-MoS2 composites and investigated their adsorption removal of the organic pesticide paraquat (PQ) for the first time. The results showed that the adsorption capacity of Ti3C2-MoS2 composites was significantly improved compared to that of Ti3C2, which might be attributed to the increase in specific surface area after the introduction of flowerlike MoS2. The adsorption process was found to follow the Freundlich isotherm model and quasi-second-order kinetic model, suggesting multilayer adsorption involving both physical and chemical adsorption.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)