期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 7, 期 8, 页码 1467-1487出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201800290
关键词
C-C bond formation; C-N bond formation; heterocycles; indoles; transition metals
资金
- National Research Foundation of Korea (NRF) - Korean government (MSIT) [2012M3A7B4049644, 2014-011165, 2015R1A2A2A01002559, 2018R1A2A2A05018392]
Indoles are important structural motifs that are commonly found in a diverse array of natural products, pharmaceuticals, and other functional molecules. Consequently, the development of new, more efficient synthetic methods for the construction of substituted indoles continues to be of great importance and considerable interest. Over the past few decades, metal-catalyzed C-C/C-N bond-forming reactions have emerged as a powerful synthetic strategy for heterocyclic synthesis. In this review, we have provided a brief overview of recent advances in the metal-catalyzed synthesis of substituted indoles through the construction of the pyrrole nucleus of indoles, involving the formation of multiple C-C/C-N bonds.
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