Article
Chemistry, Multidisciplinary
Xintao Ma, Yinggan Zhang, Tingting Fan, Diye Wei, Zongyi Huang, Zhihao Zhang, Zheng Zhang, Yunyun Dong, Qiming Hong, Zhou Chen, Xiaodong Yi
Summary: Electrochemical carbon dioxide reduction reaction (CO2RR) using clean electric energy is a sustainable method for generating valuable chemicals and fuels, contributing to the carbon-neutral cycle. However, achieving high selectivity and narrow product distribution with Cu-based electrocatalysts is still challenging. In this study, sulfur modification on different crystal planes of cuprous oxide (Cu2O) demonstrated an improvement in formate generation. The modification effectively lowered the formation energy of key intermediate *OCOH for formate generation on the Cu2O (100) facet compared to Cu2O (111) facet. This highlights the effectiveness of p-Block element modification for optimizing key intermediate adsorption energy during CO2RR.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hui Li, Peiping Yu, Renbo Lei, Feipeng Yang, Peng Wen, Xiao Ma, Guosong Zeng, Jinghua Guo, Francesca M. Toma, Yejun Qiu, Scott M. Geyer, Xinwei Wang, Tao Cheng, Walter S. Drisdell
Summary: Catalysts based on Cu nanocrystals with ultrathin Al2O3 overcoating show significantly improved selectivity and stability in electrochemical CO2-to-C2+ conversion, with a C2H4 faradaic efficiency as high as 60.4% at a current density of 300 mA cm(-2). The Al2O3 overcoating effectively suppresses the dynamic mobility and aggregation of Cu nanocrystals, leading to negligible activity loss during stability tests.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Alexander Gloystein, Jack Anthony Creed, Niklas Nilius
Summary: This work explores the nature of the (root 3 x root 3)R30 degrees reconstruction of the Cu2O(111) surface. It confirms that the nanopyramidal reconstruction model is valid for both thin films and bulk samples, and provides a detailed characterization of the reconstructed surface using STM and conductance spectra measurements.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Physical
Yu Jiang, Tong Xia, Liuxue Shen, Junlin Ma, Hongting Ma, Tongrui Sun, Fengjuan Lv, Nan Zhu
Summary: Recent developments in utilizing electrocatalysis for wearable enzyme-free biosensors and biofuel cells have shown that facet-controlled cuprous oxide nanostructures, particularly cuboctahedral Cu2O with a hollow structure, exhibit optimal sensing performance for glucose detection. The facet-dependent sensing process reveals that Cu2O{100} and Cu2O{111} facets are beneficial in improving interaction with enzyme-free substrates and accelerating electron transfer.
Article
Chemistry, Physical
Ruyue Guo, Jiayuan Chang, Huayi Li, Jie He, Peng Pan, Zhengchun Yang, Jun Wei
Summary: In this study, Cu2O@Cu composites were synthesized using a two-step liquid-phase reduction method for adsorption of methyl orange pollutant. The adsorption process followed pseudo-first-order kinetic and Freundlich isotherm, with the maximum capacity of the adsorbent being 498 mg/g. The adsorption mechanism was identified as electrostatic attraction between the positively charged adsorbent and the sulfonic acid group of MO.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Environmental
Huarui Li, Panpan Zhang, Yan Guo, Jialin Jia, Shaobin Wang, Xiaoguang Duan, Fuyi Cui, Shanshan Gao, Jiayu Tian
Summary: This study synthesized transition metal-doped cuprous oxides through a facile route and evaluated their efficiency in degrading BPA with PMS. Fe-doped Cu2O showed ultrahigh activation efficiency for PMS and catalytic degradation of BPA. The presence of trace-level free radicals and the formation of a surface-confined intermediate provided new mechanistic insights into nonradical oxidation.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Materials Science, Ceramics
Sangamithra Nehru, Sharmiladevi Ramamoorthy, Chandran Murugan, Anandhakumar Sundaramurthy
Summary: A simple and one-step hydrothermal method was developed to synthesize highly active catalytic Cu2O microcubes, and their catalytic activity for converting p-nitrophenol into p-aminophenol was investigated. The results showed that the formed Cu2O microcubes exhibited enhanced catalytic activity, and the {110} and {111} facets were identified as the predominant active sites. The positive charge resulted from the dangling Cu atoms on the {110} and {111} facets enhanced the adsorption of hydride ions.
CERAMICS INTERNATIONAL
(2022)
Article
Nanoscience & Nanotechnology
I-Hsiang Tseng, Yu-Hsuian Yang, Yi-Ting Chen, Liang-Ching Hsu
Summary: Naturally hierarchical nanostructures of leaves were replicated on polyimide films to obtain biomimetic substrates for p-type semiconductor Cu2O. The chemical states of Cu2O and hydrophobicity on the photocatalytic films were adjustable by varying the process time. The obtained films showed activity in converting CO2 into CO under visible light illumination, and the production rate of CO could be further improved by tailoring the amount and composition of copper oxides.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Lijuan Zhang, Xiaoyu Zhang, Shuhan Hui, Yandong Han, Zhenzhen Huang, Renguo Xie, Wensheng Yang
Summary: By using histidine as a shape-directing agent, we demonstrated a facile approach to form silver octopods with tunable size and localized surface plasmon resonance. The resulting silver octopods showed well-reproducible surface-enhanced Raman scattering (SERS) signals, making them suitable substrates for quantitative SERS detection.
MATERIALS CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Meng Wang, Jie Chen, Zhangliu Tian, Wenrui Dai, Baihua Cui, Xinhang Cui, Dong Wang, Yukun Xiao, Xu Lian, Chonglai Jiang, Haotian Yang, Yihe Wang, Zejun Sun, Yishui Ding, Yi-Yang Sun, Jia Zhang, Wei Chen
Summary: Research reveals that by adjusting the surface structure of WO3 photocathodes, the formation of Li2O2 can be controlled and the photocatalytic reaction activity can be enhanced. Additionally, the (002) facet is found to have higher oxidation ability, resulting in an ultralow polarization overpotential and high discharge capacity over the (002) facet dominated WO3 photocathode.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Chen Han, Varun Kundi, Zhipeng Ma, Cui Ying Toe, Priyank Kumar, Constantine Tsounis, Junjie Jiang, Shibo Xi, Zhaojun Han, Xunyu Lu, Rose Amal, Jian Pan
Summary: The initial exposed facets of Cu2O microcrystals have a direct influence on their structural transformation and product selectivity. The low-index facet tends to maintain its original structure and results in the production of 2-electron transfer products, while the high-index facet undergoes a drastic reconstruction, leading to the formation of C2+ products. This study is of great significance for the preparation and modification of catalyst materials.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Mario Kurniawan, Michael Stich, Mayra Marimon, Magali Camargo, Ralf Peipmann, Thomas Hannappel, Andreas Bund
Summary: Research has demonstrated the efficient preparation of porous Cu2O photocathodes using electrodeposition methods, showing superior performance in PEC water splitting compared to flat Cu samples.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Xiaojing Zhang, Xin Zhao, Ke Chen, Yingying Fan, Shilei Wei, Wensheng Zhang, Dongxue Han, Li Niu
Summary: This study established a matched band alignment between Pd nanoparticles and Cu2O {100} facets, enhancing the photocatalytic generation of CO by facilitating the transfer of photoholes to Pd nanoparticles. The incorporation of Pd also alleviated the photocorrosion of Cu2O, promoting its photocatalytic stability.
Article
Chemistry, Physical
V. Ratia-Hanby, E. Isotahdon, X. Yue, P. Malmberg, C. Leygraf, E. Huttunen-Saarivirta
Summary: The surface films formed on pre-oxidized copper in anoxic simulated groundwater with sulphide were characterized using various techniques. The results revealed that the sulphide content in the groundwater significantly influenced the morphology and composition of the surface film.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Physical
Yingying Song, Xiaojun Zhao, Xinyan Feng, Limiao Chen, Tiechui Yuan, Fuqin Zhang
Summary: In this work, a Z-scheme Cu3V2O7(OH)(2).2H(2)O/Cu/Cu2O heterojunction was fabricated for the first time and used as photocatalysts for CO2 reduction. The optimized CVO/Cu/Cu2O showed a significantly improved photocatalytic performance with a high CO evolution rate and maintained stability even after multiple reactions.
ACS APPLIED ENERGY MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Michael H. Huang, Gautam Kumar
Summary: By predicting the structural changes of the surface layer through density functional theory calculations, the different physical phenomena such as electrical conductivity, light absorption, and light emission on different crystal faces of semiconductor crystals can be explained. X-ray diffraction and high-resolution transmission electron microscopy analyses also begin to suggest the presence of this surface layer.
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Jing-Wei Chen, Arnab Pal, Bo-Hao Chen, Gautam Kumar, Subhodeep Chatterjee, Kiran Peringeth, Zong-Hong Lin, Michael H. H. Huang
Summary: This study successfully synthesizes various forms of BaTiO3, including octahedra, edge- and corner-truncated cubes, and cubes with four tunable sizes. Acetic acid treatment removes BaCO3 impurities, and Rietveld refinement confirms the crystal structure is tetragonal. The crystals' physical properties vary with their size and facet. BaTiO3 octahedra exhibit better performance than truncated cubes and cubes, especially in piezoelectric nanogenerators.
Article
Chemistry, Multidisciplinary
Sourav Rej, S. M. Hossein Hejazi, Zdenek Badura, Giorgio Zoppellaro, Sergu Kalytchuk, Stepan Kment, Paolo Fornasiero, Alberto Naldoni
Summary: This study presents a strategy for preparing and applying titanium dioxide nanosheets for photocatalytic hydrogen (H2) production. It was found that 2D semiconductor nanosheets decorated with single atomic species (SAs) showed high activity under light illumination, successfully forming widely dispersed SAs and exhibiting self-activation and amplification behavior beneficial for enhancing H2 production rate.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Physical
Sourav Rej, Eva Yazmin Santiago, Olga Baturina, Yu Zhang, Sven Burger, Stepan Kment, Alexander O. Govorov, Alberto Naldoni
Summary: In this study, we successfully fabricated TiN nanobars with high carrier density using a two-step method based on the synthesis of TiO2 nanowires and subsequent high temperature annealing in an ammonia flow. The resulting nanobars showed a rich set of optical resonances in the visible to mid-infrared (MIR) range. TiN nanobars decorated with Pt co-catalyst nanocrystals exhibited enhanced photocatalytic activity for hydrogen evolution under near-infrared excitation, and also demonstrated strong surface enhanced infrared absorption (SEIRA) effect for the detection of furfural molecular vibrations in the MIR region.
Article
Nanoscience & Nanotechnology
Mu-Han Hsieh, Zhe-Hong Su, Er-Ting Wu, Michael H. Huang
Summary: Cu2O rhombic dodecahedra and cubes functionalized with 4-nitrophenylacetylene were used as photocatalysts for the oxidation of aryl sulfides to produce aryl sulfoxides. Under the supply of oxygen and blue LED light, the reaction could be completed in 12 hours in a water and methanol mixed solution. High product yields and excellent selectivity for sulfoxides over sulfones were achieved, with a thioanisole to methyl phenyl sulfoxide yield of 98%. Mechanistic study revealed the involvement of photogenerated electrons, holes, and superoxide radicals in the oxidation reaction. The simple preparation of the photocatalyst and molecular functionalization demonstrate the effectiveness of surface-controlled ionic solids as photocatalysts for organic transformations.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Zhe-Hong Su, Mu-Han Hsieh, Zong-Li Chen, Wan-Ting Dai, Er-Ting Wu, Michael H. Huang
Summary: The high photocatalytic activity of Cu2O rhombic dodecahedra bounded by {110} surfaces indicates their potential in catalyzing organic transformations using photogenerated electrons, holes, and radicals. Compared to other shapes of Cu2O particles, Cu2O rhombic dodecahedra show the best photocatalytic hydroxylation yield for the conversion of 4-methoxyphenylboronic acid to 4-methoxyphenol in water and at room temperature. The presence of a hole acceptor and surface control also play important roles in the catalyst performance.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Physical
Chien-Kai Chen, Bo-Hao Chen, Michael H. Huang
Summary: Rock salt-phase MnS nanocubes with tunable sizes exhibit facet-dependent optical and electrical conductivity behaviors and magnetic properties. The surface lattice significantly affects the properties of the MnS crystals.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Physical
Er-Ting Wu, Michael H. Huang
Summary: Functionalized Cu2O rhombic dodecahedra with 4-nitrophenylacetylene (4-NA) are effective photocatalysts for oxidative amine coupling reactions, achieving high product yields under light irradiation.
Article
Materials Science, Multidisciplinary
Hsueh-Heng Ma, Michael H. Huang
Summary: Cu2O crystals of different sizes and facets were synthesized and their photoelectrochemical (PEC) activities were compared. Cubes exhibited the highest photon-to-current efficiency under front-side illumination, while octahedra had the lowest charge transfer resistance but weak photosensitivity. Rhombic dodecahedra showed hindered hole transport but greatly enhanced photocurrent under back-side illumination. Cuboctahedra with {100} and {111} faces had intermediate PEC responses. The PEC performance correlated strongly with the exposed faces but not with the band diagrams.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Multidisciplinary
Gautam Kumar, Zong-Li Chen, Satyaranjan Jena, Michael H. Huang
Summary: Transparent {100} and {111} SrTiO3 wafers have visible color differences, different absorption spectra, and band gaps of 3.04 and 3.06 eV for the {100} and {111} wafers, respectively. The {110} side faces of these wafers are exposed for electrical conductivity measurements, and the {111} face is more conductive than the {110} face, while the {100} face has the lowest conductivity. The wafers can potentially be used to fabricate transistors utilizing the electrical facet effect.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Physical
Zong-Li Chen, Michael H. Huang
Summary: Different morphologies of SrTiO3 crystals exhibit varied optical behaviors. Among them, {100}-truncated rhombic dodecahedra show superior photocatalytic activity with high reaction yield. These perovskite crystals are affordable and easy to synthesize, making them attractive photocatalysts for other organic transformations.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Materials Science, Multidisciplinary
Gautam Kumar, Chong-Rui Chen, Bo-Hao Chen, Jing-Wei Chen, Michael H. Huang
Summary: CdO stellated octahedra, octahedra, {100}-truncated octahedra, and Cd(OH)(2) hexagonal plates were synthesized by increasing cadmium acetate and KOH amounts in ethanol and heating at 150°C for 2 hours. The evolution in particle shape is attributed to changes in free energy, with all samples exhibiting high crystal quality.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Materials Science, Multidisciplinary
Gautam Kumar, Jing-Wei Chen, Hsueh-Heng Ma, Xing-Fu Huang, Michael H. Huang
Summary: This study investigates the conductivity and emission properties of Intrinsic {0001} 4H-SiC wafer on different crystal surfaces. The results show that the {0001} face has higher conductivity and emission intensity, while the {1010} face has lower values. Novel transistors can be fabricated using the {0001}/{1010} facet combination. Additionally, the SiC wafer exhibits clear photoconductivity properties.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Materials Science, Multidisciplinary
Shang-Ju Chan, Jui-Cheng Kao, Po-Jung Chou, Yu-Chieh Lo, Jyh-Pin Chou, Michael H. Huang
Summary: Research has shown that functionalized Cu2O crystals exhibit significantly improved photocatalytic activity. The modified Cu2O surfaces have good electron transfer properties and can generate hydroxyl radicals, enhancing the efficiency of the photocatalytic reactions.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Physical
Chih-Shan Tan, Michael H. Huang
Summary: Density functional theory calculations reveal that GaN crystals with different numbers of layers and different crystal planes exhibit distinct band structures and bond lengths. These findings suggest that surface layer structural deviations may influence the properties of materials.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)