期刊
RSC ADVANCES
卷 8, 期 42, 页码 24021-24028出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra02948b
关键词
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资金
- Kyoto University Nano Technology Hub in Nanotechnology Platform Project - Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- JICA under IITH-JICA 'Friendship' project
Dehydrogenative cross-coupling (DCC) is a clean methodology to make C-C bonds by using abundant C-H bonds. The blended catalyst, developed in this study, consists of a TiO2 photocatalyst and an Al2O3 supported Pd-Au bimetallic catalyst and shows superior activity to the conventional TiO2 photocatalyst loaded with the corresponding metal co-catalyst for the direct DCC between various arenes and tetrahydrofuran, with concomitant evolution of hydrogen gas. The reactions were done under mild conditions without consuming any oxidising agent or other additional chemicals. This new approach of separating the photocatalyst and the metal catalyst parts allows their independent modification to improve the overall catalytic performance.
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