期刊
RSC ADVANCES
卷 8, 期 6, 页码 2978-2985出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra13378b
关键词
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资金
- Ministry of Higher Education (MOHE) under the FRGS research grant [03-02-13-1350FR]
- Universiti Putra Malaysia (UPM) under the FRGS research grant [03-02-13-1350FR]
In this research, tannin (TA) extracted from Acacia mangium and a cationic surfactant, cetyltrimethylammonium bromide (CTAB), were used to modify and enhance the physical and electrochemical properties of a polypyrrole (PPy) composite. Brunauer-Emmett-Teller (BET) analysis presented a higher degree of surface area and porosity for the PPy/TA/CTAB nanocomposite. A highly porous and rod like structure with a lumpy surface was observed for PPy/TA prepared in the presence of CTAB by Field Emission Scanning Electron Microscopy (FESEM) and Transmission Electron Microscopy (TEM). Cyclic voltammograms of the modified SPE electrode using PPy/TA/CTAB displayed an enhanced current response compared to the electrode modified with only PPy or PPy/TA. Electrochemical Impedance Spectroscopy (EIS) exhibited a lower value of charge transfer resistance (Rct) and higher electron transfer for the modified electrode, making the nanocomposite a promising candidate for biosensor application.
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