Article
Chemistry, Multidisciplinary
Weixia Lv, Lucheng Li, Jun Chen, Caixia Ou, Qian Zhang, Shengwen Zhong, Hua Wang, Lijue Wu, Haikuo Fu
Summary: The novel high-voltage electrolyte additive TTD was found to significantly improve the capacity, cycle stability, and rate capability of batteries at high voltages. It effectively inhibits electrolyte decomposition by forming a stable cathode electrolyte interphase film. This additive could offer a cost-effective solution for high-performance high-voltage electrolytes.
Article
Chemistry, Physical
Jong Won Park, Doh Hee Park, Soohyun Go, Dae-Hyun Nam, Jihun Oh, Young-Kyu Han, Hochun Lee
Summary: In this study, a dual-functional electrolyte additive, lithium tetrafluoro(fluoromalonato)phosphate (LFMP), was synthesized to improve the thermal stability of LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode and graphite anode materials. LFMP additive showed excellent cyclability, storage performance, and mitigated gas evolution compared to its boron analog, lithium difluoro(fluoromalonato)borate (LFMB). The advantages of LFMP can be attributed to the superior cathode electrolyte interphase (CEI) and solid electrolyte interphase (SEI) layers derived from LFMP, which exhibit strong binding with O-2(center dot-) and weak binding with PF5, and favorable LiF formation.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Thuy Duong Pham, Kyung-Koo Lee
Summary: The study introduces 1,2-diethoxyethane (DEE) as a new electrolytic solvent for lithium metal batteries (LMBs), which shows improved cycling stability and Coulombic efficiencies. The use of DEE helps in reducing dendrite growth, preventing unwanted side-reactions, and creating possibilities for high-energy-density rechargeable LMBs.
Article
Chemistry, Multidisciplinary
Tao Ma, Youxuan Ni, Diantao Li, Zhengtai Zha, Song Jin, Weijia Zhang, Liqun Jia, Qiong Sun, Weiwei Xie, Zhanliang Tao, Jun Chen
Summary: By using a weakly solvating ether electrolyte, a stable cathode electrolyte interphase (CEI) can be formed on the sulfurized polyacrylonitrile (SPAN) electrode, effectively blocking the dissolution of polysulfides into the electrolyte, thus improving the electrochemical performance and cycle life of the battery.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Fengwei Bai, Yan Li, Ziyu Chen, Yongchao Zhou, Chengzong Li, Tao Li
Summary: This study demonstrates the targeted stabilization of solid electrolyte interphase (SEI) and cathode electrolyte interphase (CEI) in high-voltage lithium-metal batteries by asymmetrically sustained-releasing different additives. The strategy successfully addresses issues like dendrites growth, parasitic side reactions, and transition metals dissolution under high-voltage, resulting in a high capacity retention rate.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Jiandong Liu, Mingguang Wu, Xin Li, Daxiong Wu, Huaping Wang, Junda Huang, Jianmin Ma
Summary: Constructing robust electrode electrolyte interphases (EEIs) with polar amide groups and a Li3N/LiF heterostructure can enhance the charge cut-off voltage of LiCoO2 at 4.6 V, improving the battery density and addressing the challenge of structural instability.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Hye Ji Song, Seong Ho Oh, Yongho Lee, Jeonghan Kim, Taeeun Yim
Summary: Using calcium phosphate as a coating precursor for surface modification improves the stability and cycling retention of layered nickel-rich cathode materials, while preventing electrolyte decomposition at high temperatures. The artificial cathode-electrolyte interphases formed during surface modification play a key role in inhibiting undesired surface reactions and enhancing electrochemical performances.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Gaoxue Jiang, Jiandong Liu, Jian He, Huaping Wang, Shihan Qi, Junda Huang, Daxiong Wu, Jianmin Ma
Summary: This study proposes a novel electrolyte additive to optimize the electrode electrolyte interface and address the issues caused by high voltage. The additive can form a dense and stable solid electrolyte interphase, suppress the growth of lithium dendrites, and enhance lithium ion transport efficiency. Additionally, it can protect the electrolyte interface from corrosion. Experimental results demonstrate that lithium batteries using this electrolyte exhibit improved cycling life and energy density under high voltage.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Physical
Yu Wu, Xiang Liu, Li Wang, Xuning Feng, Dongsheng Ren, Yan Li, Xinyu Rui, Yan Wang, Xuebing Han, Gui-Liang Xu, Hewu Wang, Languang Lu, Xiangming He, Khalil Amine, Minggao Ouyang
Summary: As electric vehicle development progresses with the adoption of aggressive cathodes to improve batteries' energy density, the need to enhance safety becomes increasingly urgent. In-situ controllable formation of robust cathode-electrolyte interphase (CEI) with high inorganic content appears to be a promising strategy to address thermal runaway concerns. Emphasizing the thermal stability of cathodes after CEI modification and conducting safety tests at various levels is encouraged for comprehensive evaluation and future advancements in battery safety.
ENERGY STORAGE MATERIALS
(2021)
Article
Engineering, Environmental
Xianjun Weng, Yanyang Qin, Xinyu Da, Yuanjun Zhao, Xuetian Deng, Bo Wen, Manying Cui, Xiangkai Yin, Yaqiong Su, Jiangxuan Song, Shujiang Ding, Xiaofei Hu, Guoxin Gao, Xuefei Li
Summary: A novel bifunctional electrolyte additive, NFSI, was developed to greatly improve the cyclability and safety of lithium metal batteries. NFSI preferentially reacts with the lithium anode to form a stable solid electrolyte interphase (SEI) film, inhibiting electrolyte consumption and lithium dendrite growth. Additionally, NFSI is preferentially oxidized to form a conductive thin film layer. Li||Li cells containing 0.1 M NFSI exhibit excellent cycle stability and Li||Cu cells show high Coulombic efficiency.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Yuyao Zhang, Xiaoying Zhu, Dan Kai, Yinzhu Jiang, Qingyu Yan, Baoliang Chen
Summary: By using konjac glucomannan as a multifunctional binder to build stable solid permeable interface films, the performance of sodium ion battery cathodes is enhanced. Konjac glucomannan demonstrates strong adhesion, solid permeable interface films, and facilitates the transfer of electrons and Na+ ions to improve the cycling durability and rate capability of the batteries.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Multidisciplinary
Ling Lv, Haikuo Zhang, Jinze Wang, Di Lu, Shuoqing Zhang, Ruhong Li, Tao Deng, Lixin Chen, Xiulin Fan
Summary: A novel multifunctional additive, 7-Anilino-3-diethylamino-6-methyl fluoran (ADMF), is designed for high-voltage cathodes with unique characteristics such as preferential adsorption, oxygen scavenging, and electropolymerization protection. ADMF effectively improves the growth of the cathode-electrolyte interphase (CEI), reduces the dissolution of transition metal (TM) ions, and decreases the interface impedance, thereby enhancing the cycling stability of lithium-ion batteries. This study highlights the potential of additive design strategy in modulating CEI chemistry and has profound implications for the development of next-generation high-voltage LIBs.
Review
Chemistry, Analytical
Behrooz Mosallanejad, Shaghayegh Sadeghi Malek, Mahshid Ershadi, Hossein Sharifi, Ahmad Ahmadi Daryakenari, Farshad Boorboor Ajdari, Seeram Ramakrishna
Summary: The formation of unstable SEI layers in non-aqueous electrolytes is a major issue for the long-life cycling of rechargeable batteries, especially at high temperatures. Including a small dose of VC additive in the batteries' electrolyte can help overcome this problem. VC has shown great potential in building protective layers with good integrity and thermal stability at anodes. This review summarizes recent advances in the application of VC in electrolytes of rechargeable batteries.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Review
Electrochemistry
Huaping Wang, Xin Li, Fang Li, Xinhua Liu, Shichun Yang, Jianmin Ma
Summary: The Cathode electrolyte interphase (CEI) is important for sustaining full cell life. This mini-review focuses on the formation mechanism, modification methods, and future perspective of CEI, aiming to provide rational guidelines for high-performance LIBs.
ELECTROCHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Lihua Chu, Yuxin Shi, Ze Li, Changxu Sun, Hao Yan, Jing Ma, Xuchen Li, Chaofeng Liu, Jianan Gu, Kai Liu, Lehao Liu, Bing Jiang, Yingfeng Li, Meicheng Li
Summary: This review summarizes the principles, compositions, and models of the solid electrolyte interphase (SEI) on the anode in lithium batteries, including the functions and influences of the electroactive materials. The differences in SEI on different types of anode materials, as well as the selection and design of electrolytes, are detailedly clarified. Furthermore, the design strategies for achieving a stable and efficient SEI are outlined and discussed. Finally, the challenges and prospects of artificial SEI technology for the development of high-efficiency batteries are briefly proposed.
Article
Environmental Sciences
M. I. Ahmad, N. Bensalah
Summary: In this study, the degradation of chloranilic acid using H2O2 alone and with Fe2+ catalyst was investigated to understand a novel metal-independent approach. The addition of Fe2+ enhanced the degradation kinetics and reduced H2O2 dosage, resulting in high TOC removal. The combination of Fenton reagent with chloranilic acid shows promise as an alternative method for water and soil treatment.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2022)
Article
Nanoscience & Nanotechnology
Shunrui Luo, Kostiantyn Turcheniuk, Lihua Chen, Ah-Young Song, Wenqiang Hu, Xiaolei Ren, Zifei Sun, Rampi Ramprasad, Gleb Yushin
Summary: We report a new synthesis pathway for Mg n-propoxide nanowires from Mg ethoxide nanoparticles. The morphology transformation from nanoparticles to nanowires was studied using characterization techniques such as SEM, FTIR, and NMR spectroscopy. The ligand exchange and increased fraction of OH groups greatly enhanced Mg alkoxide bonding and facilitated the formation and growth of the Mg n-propoxide nanowires.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Daniel J. Rodriguez, Chris Y. Lau, Abigail M. Friese, Alexandre Magasinski, Gleb Yushin, Scott L. Anderson
Summary: This study measured the oxidation and sublimation kinetics of individual nanoparticles from different feedstocks using single-nanoparticle mass spectrometry. The results showed that oxidation is highly sensitive to surface structure, while sublimation rates are influenced by temperature. All types of carbon nanoparticles eventually became inert to oxygen, but the evolution and time dependence varied for nanoparticles from different feedstocks.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Biochemistry & Molecular Biology
Marwa El-Azazy, Insharah Ahsan, Nasr Bensalah
Summary: In this study, new electrochemical sensors based on the modification of glassy carbon electrode with multiwalled carbon nanotubes and rare metal oxides were fabricated. These sensors showed higher sensitivity and lower detection limits for sulfonamide drugs in water and biological samples.
Article
Materials Science, Multidisciplinary
Christian Randell Arro, Assem Taha Ibrahim Mohamed, Nasr Bensalah
Summary: This study investigates the effect of different Ge mass loadings on the electrochemical performance of GeO2/Ge/r-GO composite anodes. The results demonstrate that the composite anode with a Ge mass loading of 25% exhibits the highest cycling retention and average specific capacity. The composite with 50% Ge mass loading shows the advantageous characteristics of both composites, maintaining good cycling performance and high specific capacity.
MATERIALS TODAY COMMUNICATIONS
(2022)
Review
Chemistry, Physical
Yannis De Luna, Nasr Bensalah
Summary: The application of synthetic diamond-based electrodes, especially boron-doped diamond, in water treatment has shown promising potential. Further research is needed on the synthesis of low-cost BDD anodes and their feasibility in removing EDCs.
CURRENT OPINION IN ELECTROCHEMISTRY
(2022)
Article
Nanoscience & Nanotechnology
Zifei Sun, Baichuan Wang, Matthew G. Boebinger, Alexandre Magasinski, Samik Jhulki, Yawei Zhang, Wenbin Fu, Matthew T. McDowell, Gleb Yushin
Summary: In this study, the performance of iron trifluoride (FeF3) in multiple types of ionic liquid (IL) electrolytes was significantly improved, particularly in terms of cycling stability at both room temperature and elevated temperatures. The IL electrolytes formed a protective and ionically conductive cathode electrolyte interphase (CEI) layer during cycling, reducing side reactions. Additionally, the ILs exhibited higher ionic conductivity and lower viscosity at elevated temperatures, enabling higher accessible capacity.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Yannis De Luna, Nasr Bensalah
Summary: In this study, a nickel niobate compound (NiNb2O6) was successfully synthesized through a facile and scalable method based on solid-state reaction. The as-prepared NiNb2O6 exhibited excellent electrochemical performance, including high specific charge capacity, stable cyclability, and high capacity retention.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Wenqiang Hu, Wenbin Fu, Samik Jhulki, Liang Chen, Aashray Narla, Zhijian Sun, Fujia Wang, Alexandre Magasinski, Gleb Yushin
Summary: In this study, a heat-resistant and flame-retardant porous composite membrane composed of polyetherimide (PEI) and Al2O3 nanowires (NWs) is developed to address the poor heat and flame-resistance of polyolefin separators and the high flammability of organic electrolytes. The composite membranes demonstrate excellent flexibility, thermal stability, and flame-retardancy, surpassing the performance of conventional polyolefin separators. They also exhibit superior wettability, higher ionic conductivity, larger electrolyte uptake, and improved cycle and rate performance in lithium-ion batteries.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Review
Energy & Fuels
Wadha Al-Hajri, Yannis De Luna, Nasr Bensalah
Summary: Carbon materials play an important role in various applications, and the addition of dopants, such as nitrogen, can improve their properties. Nitrogen-doped carbon materials have shown great potential in CO2 capture, energy conversion, and energy storage. However, factors like synthesis method, starting materials, doping level, and porosity need to be deeply studied. This review discusses the synthesis methods of nitrogen-doped carbon materials and their recent progress in CO2 adsorption, energy conversion, and energy storage applications, as well as the remaining issues and possible strategies to overcome them.
Article
Nanoscience & Nanotechnology
Mengting Liu, Satnik Jhulki, Alexandre Magasinski, Peng-Fei Wang, Gleb Yushin
Summary: Researchers synthesized hierarchically porous TiO2-x/C nanofibers with axially aligned cylindrical tunnel pore channels as a host for sulfur in lithium-sulfur batteries. The unique structure and enhanced conductivity of the materials enable high sulfur loading and reduced shuttle effect.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Nasr Bensalah, Emna Neily, Ahmed Bedoui, Mohammad I. Ahmad
Summary: The Fenton system, a simple and efficient advanced oxidation technology, is used for the treatment of organic micropollutants in water and soil. This study aimed to replace the homogeneous catalyst with a heterogeneous natural iron-based catalyst, which showed high catalytic activity in decomposing H2O2 into hydroxyl radicals. The natural iron-based catalyst can function at any pH level without the need for pH control, and can be reused after heat treatment.
Article
Chemistry, Physical
Wenbin Fu, Doyoub Kim, Fujia Wang, Gleb Yushin
Summary: The past 30 years have seen significant advances in lithium-ion batteries, reshaping various aspects of our daily life. However, current Li-ion batteries are unable to meet the growing market demands. To overcome this challenge, it is crucial to understand the fundamentals of battery chemistries and consider both the anode and cathode, as well as their interphases. While previous research has focused on anodes and their solid-electrolyte interphase (SEI), there is a lack of reviews and analysis on the materials and interfacial issues of the cathode side. In this article, we provide a critical overview of the current status and challenges for Li-ion battery cathodes and their solid electrolyte interphase (CEI), discussing their impact on cathode performance characteristics and proposing design guidelines for future Li-ion batteries.
JOURNAL OF POWER SOURCES
(2023)
Article
Materials Science, Multidisciplinary
Fujia Wang, Zhijian Sun, Samik Jhulki, Wenbin Fu, Kostiantyn Turcheniuk, Billy Johnson, Doyoub Kim, Crystal Jain, Ah-Young Song, Yawei Zhang, Kaixi Chen, Aashray Narla, Wenqiang Hu, Dov Wallack, Chingping Wong, Gleb Yushin
Summary: This study reports a cost-effective and scalable method using water as an intermediary solvent to transform bulk aluminum-lithium alloys into ceramic alumina nanowires and aerogels. The use of water overcomes the limitations of conventional methods and offers a low-cost and environmentally-friendly route for the synthesis of ceramic nanowires. The resulting alumina nanowire aerogels, when infiltrated with epoxy, show significantly improved thermal properties as a high-performance thermal interface material for electronic devices.
ACS MATERIALS LETTERS
(2023)
Article
Nanoscience & Nanotechnology
Aashray Narla, Wenbin Fu, Alp Kulaksizoglu, Atsushi Kume, Billy R. Johnson, Ashwin Sankara Raman, Fujia Wang, Alexandre Magasinski, Doyoub Kim, Mohammed Kousa, Yiran Xiao, Samik Jhulki, Kostiantyn Turcheniuk, Gleb Yushin
Summary: Current lithium-ion battery separators made from polyolefins suffer from low porosity, low wettability, and slow ionic conductivity, leading to potential safety hazards. To address these issues, a composite membrane made of poly(vinylidene fluoride-co-hexafluoropropylene) nanofibers functionalized with nanodiamonds (NDs) is introduced, which exhibits thermal resistance, mechanical robustness, and ionic conductivity. The ND-functionalized nanofiber separator enables high-capacity and stable cycling of lithium cells, outperforming conventional polyolefin separators.
ACS APPLIED MATERIALS & INTERFACES
(2023)