期刊
ACS CATALYSIS
卷 8, 期 8, 页码 7287-7307出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b02066
关键词
perfluoroalkylation; organophotocatalysis; transition metal photocatalysis; EDA complex; FLP perfluoroalkylation; catalytic perfluoroalkylations
Recent protocols and reactions for catalytic radical perfluoroalkylations will be described. The production of perfluoroalkyl radicals (R-F = CnF2n+1, n >= 2), which effect both addition and substitution reactions on organic substrates, can be realized through a range of diverse methods such as the well-established visible-light transition-metal-mediated photocatalysis, organic-dye-photocatalyzed reactions, electron donoracceptor complexes, and more recently frustrated Lewis pairs. Thus, perfluoroalkylation reactions of carboncarbon multiple bonds, isocyanides, nitrones, hydrazones, beta-keto esters, a-cyano arylacetates, sulfides, and (hetero)arenes will be described. Special emphasis will be placed on examples published after 2015, where higher fluorinated series of fluoroalkylating reagents are studied.
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